电化学（中英文）2024，Vol.30Issue(11)：4-19,16.DOI:10.61558/2993-074X.3495
微纳米尺度两互不相溶电解质溶液界面的单颗粒碰撞电化学
Single-Entity Collisional Electrochemistry at the Micro-and/or Nano-Interface Between Two Immiscible Electrolyte Solutions
摘要
Abstract
Single-entity collisional electrochemistry(SECE)is a branch of single-entity electrochemistry.It can directly charac-terize entities/particles with single particle resolution through random collisions between particles and electrodes in a solution,and obtain rich physicochemical information,thus becoming one of the frontiers of electroanalytical chemistry in the past two decades.Interestingly,the(micro/nanoscale)sensing electrodes have evolved from a polarizable liquid/liquid(mercury/liquid)interface to a solid/liquid interface and then to a liquid/liquid interface(i.e.,an interface between two immiscible electrolyte solutions,ITIES),as if they have completed a cycle(but in fact they have not).ITIES has become the latest sensing electrode in the booming SECE due to its polarizability(up to 1.1 V at the water/α,α,α-trifluorotoluene interface)and high reproducibility.The four measurement modes(direct electrolysis,mediated electrolysis,current blockade,and charge displacement)developed in the realm of SECE at solid/liquid interfaces have also been fully realized at the miniature ITIES.This article will discuss these four modes at the ITIES from the perspectives of basic concepts,operating mechanisms,and latest developments(e.g.,discovery of ionosomes,blockade effect of Faradaic ion transfer,etc.),and look forward to the future development and direction of this emerging field.关键词
单颗粒碰撞电化学/两互不相溶电解质溶液界面/电荷转移Key words
Single-entity collisional electrochemistry/Interface between two immiscible electrolyte solutions/Charge transfer引用本文复制引用
杨丽芳,邓海强,陈俊杰,陈灵玉,金思琪,方韬雄,何思佳,沈粮骏,黄新建,孙霄航..微纳米尺度两互不相溶电解质溶液界面的单颗粒碰撞电化学[J].电化学（中英文）,2024,30(11):4-19,16.基金项目
This work was supported by the National Natu-ral Science Foundation of China(No.21904143). （No.21904143）
