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首页|期刊导航|广州化学|并列电纺Sb2O3@PMIA/TPP@PVDF-CTFE隔膜提高锂离子电池的安全性与离子传输性能

并列电纺Sb2O3@PMIA/TPP@PVDF-CTFE隔膜提高锂离子电池的安全性与离子传输性能

韩标 王珂

广州化学2024,Vol.49Issue(6):12-17,6.
广州化学2024,Vol.49Issue(6):12-17,6.DOI:10.16560/j.cnki.gzhx.20240601

并列电纺Sb2O3@PMIA/TPP@PVDF-CTFE隔膜提高锂离子电池的安全性与离子传输性能

Side-by-side Electrospun Sb2O3@PMIA/TPP@PVDF-CTFE Separators Improve Lithium-ion Battery Safety and Ion Transport Performance

韩标 1王珂1

作者信息

  • 1. 上海理工大学 材料与化学学院,上海 200093
  • 折叠

摘要

Abstract

In this study,Sb2O3@PMIA/TPP@PVDF-CTFE composite separators for lithium-ion batteries with a side-by-side structure were prepared by the side-by-side electrospinning technique,and the mechanical properties,thermal stability,flame retardancy,and electrolyte wettability of the composite separators were analyzed.The results showed that the composite separator has high mechanical properties(tensile strength of 11.7 MPa),excellent thermal stability(only slight deformation after heat treatment at 220℃for 0.5 h),good flame retardant properties and excellent electrolyte wettability,and also has a high porosity and electrolyte absorption rate(277%and 78%,respectively),and an ionic conductivity as high as 2.67 mS/cm,which is shown by the experimental results.The prepared side-by-side composite separator effectively improves the safety and ion transport capacity of the battery.

关键词

静电纺丝/并列结构/安全性能/离子传输性能/Sb2O3/PMIA/PVDF-CTFE/TPP

Key words

electrospinning/side-by-side structure/safety performance/ion transport properties/Sb2O3/PMIA/PVDF-CTFE/TPP

分类

化学化工

引用本文复制引用

韩标,王珂..并列电纺Sb2O3@PMIA/TPP@PVDF-CTFE隔膜提高锂离子电池的安全性与离子传输性能[J].广州化学,2024,49(6):12-17,6.

广州化学

1009-220X

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