Electrode/Electrolyte Optimization‑Induced Double‑Layered Architecture for High‑Performance Aqueous Zinc‑(Dual)Halogen BatteriesOA
Aqueous zinc-halogen batteries are promising candidates for large-scale energy storage due to their abundant resources,intrinsic safety,and high theoretical capacity.Nevertheless,the uncontrollable zinc dendrite growth and spontaneous shuttle effect of active species have prohibited their practical implementation.Herein,a double-layered protective film based on zinc-ethylenediamine tetramethylene phosphonic acid(ZEA)artificial film and ZnF2-rich solid electrolyte interphase(SEI)layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization.The ZEA-based artificial film shows strong affinity for the ZnF2-rich SEI layer,therefore effectively suppressing the SEI breakage and facilitating the construction of double-layered protective film on the zinc metal anode.Such double-layered architecture not only modulates Zn2+flux and suppresses the zinc dendrite growth,but also blocks the direct contact between the metal anode and electrolyte,thus mitigating the corrosion from the active species.When employing optimized metal anodes and electrolytes,the as-developed zinc-(dual)halogen batteries present high areal capacity and satisfactory cycling stability.This work provides a new avenue for developing aqueous zinc-(dual)halogen batteries.
Chengwang Zhou;Zhezheng Ding;Shengzhe Ying;Hao Jiang;Yan Wang;Timing Fang;You Zhang;Bing Sun;Xiao Tang;Xiaomin Liu
School of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaCentre for Clean Energy Technology,School of Mathematical and Physical Sciences,Faculty of Science,University of Technology Sydney,Ultimo,NSW 2007,AustraliaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of ChinaSchool of Textiles and Clothing,School of Chemistry and Chemical Engineering,Qingdao University,Qingdao 266071,Shandong,People’s Republic of China School of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang 453007,Henan,People’s Republic of China
动力与电气工程
Zn metal anodesDouble-layered protective filmElectrode/electrolyte optimizationAqueous zinc-(dual)halogen batteries
《Nano-Micro Letters》 2025 (3)
P.121-137,17
support from the National Natural Science Foundation of China(22209089,22178187)Natural Science Foundation of Shandong Province(ZR2022QB048,ZR2021MB006)Excellent Youth Science Foundation of Shandong Province(Overseas)(2023HWYQ-089)the Taishan Scholars Program of Shandong Province(tsqn201909091)Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University.
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