化工进展2024，Vol.43Issue(12)：6589-6591,3.DOI:10.16085/j.issn.1000-6613.2024-1293
烯烃氢甲酰化的电化学策略
Electrochemical strategies for hydroformylation of olefin
彭鑫鑫1
作者信息
- 1. 中国石油化工股份有限公司茂名分公司研究院,广东 茂名 525000||广东省先进绿色润滑材料企业重点实验室,广东 茂名 525000||茂名绿色化工研究院石化新材料联合实验室,广东 茂名 525000
- 折叠
摘要
Abstract
Hydroformylation of olefin mainly involves the activation of olefin and the formation of C—C bond and aldehyde group.At present,the hydroformylation of olefin is mainly achieved by thermochemical method using Rh and Co based metal catalysts,which usually requires harsh reaction conditions with high temperature and high pressure.Electrochemical methods using clean and sustainable electrical energy can provide a greater driving force and achieve hydroformylation of olefin under mild reaction conditions at room temperature and pressure compared to thermochemical methods.The applied voltage can affect the electronic structure of metal catalyst,and the rapid activation of olefin is driven by adjusting the applied voltage.In addition,electrochemical reactions can be used to provide a continuous supply of carbon and hydrogen sources for hydroformylation of olefin.Electrochemical methods will play an important role in the hydroformylation of olefin in the future.关键词
烯烃/氢甲酰化/电化学/碳源/氢源Key words
olefin/hydroformylation/electrochemical/carbon source/hydrogen source分类
化学化工引用本文复制引用
彭鑫鑫..烯烃氢甲酰化的电化学策略[J].化工进展,2024,43(12):6589-6591,3.
