化工进展2024，Vol.43Issue(12)：6723-6734,12.DOI:10.16085/j.issn.1000-6613.2023-1957
光催化用于有机物选择性转移氢化研究进展
Research progress on photocatalysis for selective transfer hydrogenation of organic compounds
摘要
Abstract
In recent decades,the development of photocatalysis has opened up new paths for the efficient utilization of energy.Transfer hydrogenation based on photocatalysis offers advantages such as the absence of gaseous hydrogen,mild reaction conditions,reliance on clean and renewable energy sources,and controllable reaction processes.In this paper,research progress in recent years on photocatalysis for selective transfer hydrogenation of organic compounds is reviewed.Firstly,the mechanism of photocatalytic transfer hydrogenation is presented.Secondly,based on the different functional groups being hydrogenated,the research achievements of various photocatalysts and reaction systems are summarized and the reaction mechanism of typical catalytic systems is explained.New hydrogenation systems and ways of substrate valorization are also introduced.Finally,it is pointed out that photocatalytic hydrogenation still encounters challenges such as low reaction rate and low quantum efficiency,limited photocatalysts suitable for visible light,incompatible to traditional reactors,and the use of power-consuming simulated light sources.In this regard,the prospects including the combination of photocatalysis and electrocatalysis,the development of new photocatalysts,the design of reactors suitable for photocatalysis,and the direct utilization of solar energy for photocatalysis,are made.关键词
催化/光化学/加氢/选择性/能源Key words
catalysis/photochemistry/hydrogenation/selectivity/energy分类
化学化工引用本文复制引用
潘晟昊,陈伦刚,张兴华,张琦,马隆龙,刘建国..光催化用于有机物选择性转移氢化研究进展[J].化工进展,2024,43(12):6723-6734,12.基金项目
国家自然科学基金(51976225) （51976225）
中央高校基本科研业务费专项(2242022R10058). （2242022R10058）
