首页|期刊导航|林产化学与工业|碱预浸渍对竹材化机浆化学成分的影响

碱预浸渍对竹材化机浆化学成分的影响OA北大核心CSTPCD

Effects of Alkali Pre-impregnation on the Chemical Components of Bamboo Chemi-mechanical Pulp

中文摘要英文摘要

对混合竹材采用预压榨、预浸渍、搓丝、碱液处理和盘磨机KRK磨浆,制备了竹材化机浆(CMP),并探讨碱预浸渍对竹材CMP化学成分及后续成纸的影响.研究结果表明:当预浸渍用碱量由2%(NaOH计,下同)增加至4%时,硝酸-乙醇纤维素提高率(对原竹片)由7.20%增加到17.89%.保持预浸渍用碱量4%时,将预浸渍废液替代部分预浸渍液,其中含10%预浸渍废液,即替代量为10%时,浆料含酸不溶木质素12.25%,灰分0.67%,苯-醇抽出物1.10%,聚戊糖8.47%,与未替代浆料(替代量0)相比,酸不溶木质素、灰分、苯-醇抽出物和聚戊糖降低率分别提高3.9%、13.05%、5.84%和5.95%;替代量10%时,浆料中综纤维素和硝酸-乙醇纤维素的质量分数分别为77.83%和64.71%,成浆得率67.30%(对原竹片);在打浆度为(30±0.5)度的条件下,替代量10%的浆料进行纸张抄造,成纸耐折度11次,耐破指数2.13(kPa·m2)/g,撕裂指数7.34(mN·m2)/g,裂断长3.20 km,环压指数 8.4(N·m)/g.

The mixed bamboo was treated with pre-press,pre-impregnation,thread rolling,lye and KRK pulping to prepare bamboo chemical mechanical pulp(CMP).The effects of alkali pre-impregnation on the chemical composition of bamboo CMP and the subsequent paper formation were discussed.The results showed that the improvement rate of nitric acid-ethanol cellulose(relative to the original bamboo slices)increased from 7.20%to 17.89%when the alkali dosage for pre-impregnation increased from 2%(measured by NaOH,the same below)to 4%.Replacing part of the pre-impregnation liquid with pre-impregnation waste liquid,the bamboo chips with 4%alkali for pre-impregnation was subjected to thread rolling,alkali treatment,KRK disk grinding and washing.When the substitution amount was 10%,the acid-insoluble lignin,ash,benzene-alcohol extract and polypentose contents in the pulp were 12.25%,0.67%,1.10%and 8.47%,respectively.Compared with unreplaced pulp(the substitution amount was 0),the reduction rates of acid-insoluble lignin,ash,benzene-alcohol extract and polypentose increased by 3.9%,13.05%,5.84%and 5.95%,respectively.When the substitution amount was 10%,the mass fractions of holocellulose and nitro-ethanol cellulose were 77.83%and 64.71%,respectively,and the pulp yield was 67.30%(for raw bamboo chips).At the beating degree of(30±0.5)SR and substitution amount of 10%,the folding strength,bursting index,tear index,break length and ring pressure index of the finished paper were 11 times,2.13(kPa m2)/g,7.34(mN·m2)/g,3.20 km and 8.4(N·m)/g,respectively.

杨玲;房桂干;谢章红;韩天杰;高志杰;李文俊

四川轻化工大学生物工程学院,四川 自贡 643000中国林业科学研究院林产化学工业研究所,江苏南京 210042四川省竹子制浆造纸工程技术研究中心,四川 宜宾 644000||宜宾纸业股份有限公司,四川 宜宾 644000

化学工程

预处理竹材化学成分物理强度

pretreatmentbamboochemical compositionphysical strength

《林产化学与工业》 2024 (006)

96-102 / 7

宜宾市科技局"揭榜挂帅"项目(2022JB009);宜宾市科技计划项目(2022JC001);四川轻化工大学2024年大学生创新项目资助(202410622023)

10.3969/j.issn.0253-2417.2024.06.011

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