六盘水师范学院学报2024，Vol.36Issue(6)：1-17,17.DOI:10.16595/j.1671-055X.2024.06.001
羰基合成:煤基合成气低碳化利用的绿色化工路线
Carbonylation Synthesis:A Green Chemical Route for Low-Carbon Utilization of Coal-Based Syngas
摘要
Abstract
Synthesis of oxygenated organic compounds from syngas represents a key technological pathway for efficient syngas utilization.This review begins with a brief analysis of the characteristics of coal chemical processes,followed by an overview of the features and advantages of carbonylation technology.Carbonylation technology efficiently utilizes the carbon and oxygen resources in coal-based syngas,eliminating unnecessary"deoxygenation"steps and promoting the enhancement of"atom economy",i.e.,maximizing the conversion of every atom in the raw material molecules into the final product.This technology has emerged as a frontier research area driving the transformation of coal-based syngas resources into high-value-added products.The paper also highlights the technical characteristics and research progress of several important carbonylation reactions,aiming to provide devel-opment strategies and guidance for synthesizing high-value-added chemicals from syngas and for constructing an industrial chain for carbonylation synthesis based on coal chemical syngas.关键词
羰基合成/合成气/煤化工/含氧化学品/催化Key words
Carbonylation synthesis/Syngas/Coal chemical industry/Oxygenated chemicals/Catalysis分类
化学化工引用本文复制引用
雷以柱,李光兴..羰基合成:煤基合成气低碳化利用的绿色化工路线[J].六盘水师范学院学报,2024,36(6):1-17,17.基金项目
国家自然科学基金项目"无机介孔材料/多孔聚合物杂化固体酸的构筑及其催化水油两相反应性能研究"(22162017) （22162017）
贵州省自然科学基金"碳基单原子催化剂设计制备、结构调控及其串联催化CO2加氢制甲醇研究"(黔科合基础-ZK[2024]重点090) （黔科合基础-ZK[2024]重点090）
贵州省高层次创新型人才"百层次人才"(黔科合平台人才-GCC[2023]049). （黔科合平台人才-GCC[2023]049）
