化工矿物与加工2025，Vol.54Issue(1)：17-22,6.DOI:10.16283/j.cnki.hgkwyjg.2025.01.003
铁精矿电化学湿法氧化脱硫试验研究
The test study of electrochemical wet oxidation desulfurization of iron concentrate
摘要
Abstract
The iron concentrate after magnetic separation and reverse flotation of an iron ore in eastern Hubei was used as raw material,and the electrochemical wet oxidation desulfurization process was adopted.The desulfurization effect was investigated by adjusting the parameters such as catalyst type,electrolyte content,electrolysis voltage,electrolysis temperature and electrolysis time.The results show that the optimum desulfurization reaction conditions in the electrochemical system are as follows:electrolyte HCl mass fraction 2.5%,catalyst MnCl2 content 2.5%,elec-trolysis voltage 3 V,electrolysis temperature 65℃,and reaction time 4 h.Under these conditions,the sulfur content of the high-sulfur iron concentrate is reduced to less than 0.3%,and the chlorine content of the ore powder after washing is extremely low.Meet the standard requirements for smelting high-quality steel;At the same time,the sulfur in the iron concentrate after desulfurization is dissolved in the electrolyte in a soluble state(SO32-and SO42-),and the electrolyte can be recycled.Electrochemical wet desulfurization has a more significant effect than other wet desulfurization methods.关键词
铁精矿/电化学法/湿法脱硫/间接氧化/硫含量/电解/催化Key words
iron concentrate/electrochemical method/wet desulfurization/indirect oxidation/sulfur content/elec-trolysis/catalysis分类
化学化工引用本文复制引用
陈小霞,贾中昊,姚容宇,张勇,程研,马敬旺,罗鹏..铁精矿电化学湿法氧化脱硫试验研究[J].化工矿物与加工,2025,54(1):17-22,6.基金项目
湖北省科技人才项目(2023DJC125) （2023DJC125）
黄石市揭榜制科技项目(2023A007). （2023A007）
