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氮掺杂生物质炭耦合氧化铜材料用于电催化还原CO2

郭天宇 张佳宁 白德豪 张金男 祁彧 王红涛

太原理工大学学报2025,Vol.56Issue(1):80-87,8.
太原理工大学学报2025,Vol.56Issue(1):80-87,8.DOI:10.16355/j.tyut.1007-9432.20230850

氮掺杂生物质炭耦合氧化铜材料用于电催化还原CO2

Nitrogen-doped Biomass Carbon Coupled with Copper Oxide Materials for Electrocatalytic Reduction of CO2

郭天宇 1张佳宁 2白德豪 3张金男 2祁彧 2王红涛2

作者信息

  • 1. 太原理工大学 环境科学与工程学院,山西 晋中||太原理工大学 气体能源高效利用山西省重点实验室,山西 太原
  • 2. 太原理工大学 环境科学与工程学院,山西 晋中
  • 3. 中石油煤层气有限责任公司忻州分公司,山西 忻州
  • 折叠

摘要

Abstract

[Purposes]Electrocatalytic technology for converting CO2 into high-value-added fuels and chemicals has promising applications.However,developing electrocatalysts with superior perfor-mance still faces significant challenges.[Methods]In this study,wheat bran was used as the precursor of biomass carbon and the pyrolysis method was used to prepare nitrogen-doped biomass carbon mate-rials(NC).By further coupling with CuO via a hydrothermal method,a series of CuO@NC composite materials were costructed.The crystalline phase,microscopic morphology,structure,and elemental valence states were analyzed by multiple characterization techniques.The electrocatalytic performance was investigated towards the electrocatalytic reduction of CO2.[Findings]Results indicate that the composite catalyst synthesized at 160℃(CuO@NC-160)exhibits high selectivity towards ethylene,with a maximum faradaic efficiency of 26.85%at-1.18 V vs.RHE.This study presents a feasible pathway for fabricating low-cost and efficient CuO-based electrocatalysts.

关键词

CuO/生物质炭/二氧化碳/电催化/还原

Key words

copper oxide/biomass carbon/carbon dioxide/electrocatalysis/reduction

分类

化学化工

引用本文复制引用

郭天宇,张佳宁,白德豪,张金男,祁彧,王红涛..氮掺杂生物质炭耦合氧化铜材料用于电催化还原CO2[J].太原理工大学学报,2025,56(1):80-87,8.

基金项目

山西省应用基础研究计划项目(202203021211158,20210302123176) (202203021211158,20210302123176)

太原理工大学学报

OA北大核心

1007-9432

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