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含氟丙烯酸酯改性制备铝颜料及其漂浮性能研究

佘娜 王智鑫 董前年 陈国庆 曹明 夏茹 陈鹏 钱家盛

安徽大学学报(自然科学版)2025,Vol.49Issue(1):77-85,9.
安徽大学学报(自然科学版)2025,Vol.49Issue(1):77-85,9.DOI:10.3969/j.issn.1000-2162.2025.01.010

含氟丙烯酸酯改性制备铝颜料及其漂浮性能研究

Preparation of aluminium pigment modified by fluorine-containing acrylate and its floating properties

佘娜 1王智鑫 1董前年 2陈国庆 2曹明 1夏茹 1陈鹏 1钱家盛1

作者信息

  • 1. 安徽大学化学化工学院,绿色高分子材料安徽省重点实验室,安徽 合肥 230601
  • 2. 合肥旭阳铝颜料有限公司,安徽 合肥 231131
  • 折叠

摘要

Abstract

In this study,a fluorine-containing acrylate modified aluminum pigment was prepared by two-step process.Firstly,a double-bond functionalized silica coating layer was formed on the surface of aluminum pigment by the synergic hydrolysis of acrylate silane coupling agent and ethyl orthosilicate under alkaline environment.Then a fluorine-containing coating layer was formed by in-situ polymerization to obtain a fluorine-containing acrylate modified aluminum pigment.The structure and properties of the modified aluminum pigment were characterized by FTIR,TG,XPS,contact Angle test,gloss test,acid and alkali corrosion resistance test,flotation test and other analytical methods.The results showed that compared with the unmodified aluminum pigments,the modified aluminum pigments had better floatability,covering power to water surface and acid and alkali resistance in coumarone resin and ethylene glycol butyl ether.

关键词

铝颜料/漂浮/含氟丙烯酸酯/表面改性/原位聚合

Key words

aluminum pigment/floating/fluorine acrylate/surface modification/in situ poly merization

分类

化学化工

引用本文复制引用

佘娜,王智鑫,董前年,陈国庆,曹明,夏茹,陈鹏,钱家盛..含氟丙烯酸酯改性制备铝颜料及其漂浮性能研究[J].安徽大学学报(自然科学版),2025,49(1):77-85,9.

基金项目

安徽省重大科技成果工程化研发资助项目(202203c08020005) (202203c08020005)

安徽大学学报(自然科学版)

OA北大核心

1000-2162

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