合成材料老化与应用2024，Vol.53Issue(6)：34-36,3.
一种星型结构芳胺类空穴传输材料的合成及性能研究
Synthesis and Performance Study of A Star-shaped Aromatic Amine Hole Transport Material
摘要
Abstract
Hole transport materials are a category of crucial organic photoelectric functional materials and are extensively utilized in the field of OLED.In this article,triphenylamine with high carrier mobility was selected as the core framework,and through a coupling reaction,spirofluorene with remarkable thermal stability and the fluorene group were introduced to synthesize the target compound N,N-bis(9,9-dimethyl-9H-fluoren-2-yl)-9,9'-spirobi[fluoren]-3-amine.The results demonstrate that the target compound possesses relatively high thermal stability,with a weight loss temperature of 405 ℃ and a glass transition temperature of 222 ℃,which is higher than the glass transition temperature(98 ℃)of commonly used small molecule hole transport materials such as NPB.Through theoretical calculation,the target compound has a relatively appropriate HOMO energy level(4.72 eV)similar to that of the commonly used prototype material ITO,and has a small potential barrier value,which is conducive to the injection of holes.It can be employed as a hole transport material with outstanding performance in optoelectronic devices such as OLED.关键词
有机发光二极管/空穴传输材料/芳胺/螺芴Key words
OLED/hole transport materials/arylamine/spirofluorene分类
化学化工引用本文复制引用
韩蒙蒙,申奥,邓书洋,杨振强,李岩..一种星型结构芳胺类空穴传输材料的合成及性能研究[J].合成材料老化与应用,2024,53(6):34-36,3.基金项目
河南省科技研发计划联合基金资助项目(225200810094) （225200810094）
河南省科技攻关计划(242102230169) （242102230169）
河南省科学院基本科研业务费项目(240603048) （240603048）
河南省科学院创新平台建设项目(23100303) （23100303）
河南省科学院特聘研究员项目(230503006). （230503006）
