极紫外多层膜氮化物和氧化物保护层的工艺研究OA北大核心
Protective layer of oxides and nitrides on the surface of extreme ultraviolet multilayers
极紫外(EUV)反射镜在高能、高功率极紫外光辐照的过程中,其表面易形成碳沉积和氧化,从而影响其反射率,进而缩短其使用寿命.针对这一问题,分别实验研究了在极紫外多层膜表面镀制氮化物和氧化物保护层的制备工艺,并进行了表征.在制备过程中,基于直流反应磁控溅射技术,研究了工艺气体流量与溅射电压之间的"双曲线"关系,以此优化控制反应气体量,进而降低反应溅射过程中反应气体对Mo/Si多层膜的影响.基于这一方法,分别在Mo/Si多层膜表面镀制TiN、ZrN和TiO2 保护层,应用掠入射X射线反射(GIXR)、X射线光电子能谱(XPS)和透射电子显微成像(TEM)对其进行了表征,并通过对比分析,验证了氮化物保护层具有一定的性能优势.
In the process of high energy and high power extreme ultraviolet(EUV)irradiation,carbon deposition and surface oxidation are easy to form on the surface of the EUV mirror,which will affect its reflectivity and shorten its service life.To solve this problem,technology of nitride and oxide capping coating on the surface of extreme ultraviolet multilayer film was studied experimentally and characterized.In the preparation process,based on DC reactive magnetron sputtering coating technology,the"hyperbola"relationship between process gas flow and sputtering voltage was studied,to optimize the control of the amount of reactive gas,and then reduce the influence of reactive gas on Mo/Si multilayer films during reactive sputtering.Based on this method,TiN,ZrN and TiO2 capping layer were plated on the surface of Mo/Si multilayer films and were characterized by grazing incident X-ray reflection(GIXR),X-ray photoelectron spectroscopy(XPS)and transmission electron microscopy(TEM).It is proved that the nitride capping layer has certain performance advantages.
王佳兴;韩伟明;张晗;匡尚奇
长春理工大学物理学院,长春 130022长春理工大学物理学院,长春 130022长春理工大学物理学院,长春 130022长春理工大学物理学院,长春 130022
物理学
极紫外多层膜反应磁控溅射表面保护层氮化物/氧化物薄膜
extreme ultraviolet multilayersreactive magnetron sputteringsurface capping layernitride/oxide thin film
《强激光与粒子束》 2025 (2)
37-45,9
国家自然基金委区域联合基金重点项目(U22A2070)
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