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费托合成直接制航空煤油中双功能催化剂的研究进展

刘津旭 吕帅帅 李红伟 周秋明 牛丛丛 徐润 李新刚

低碳化学与化工2025,Vol.50Issue(1):13-19,7.
低碳化学与化工2025,Vol.50Issue(1):13-19,7.DOI:10.12434/j.issn.2097-2547.20240152

费托合成直接制航空煤油中双功能催化剂的研究进展

Research progress on bifunctional catalysts for direct synthesis of jet fuel from Fischer-Tropsch synthesis

刘津旭 1吕帅帅 1李红伟 1周秋明 1牛丛丛 1徐润 1李新刚2

作者信息

  • 1. 中石化石油化工科学研究院有限公司,北京 100083
  • 2. 天津大学化工学院,化学工程联合国家重点实验室,化学化工协同创新中心(天津),海河可持续化学转化实验室,天津市应用催化科学与工程重点实验室,天津 300350||天津大学浙江研究院(绍兴),浙江绍兴 312300
  • 折叠

摘要

Abstract

Fischer-Tropsch synthesis(FTS)can directly convert syngas derived from biomass into jet fuel,making it one of the most promising technologies for producing bio-based jet fuel.However,the selectivity of jet fuel in direct FTS is limited by the Anderson-Schulz-Flory(ASF)distribution law,posing a significant challenge in improving selectivity of jet fuel.Bifunctional catalysts,which couple FTS active centers with zeolite acid centers,enable the relay of CO hydrogenation with secondary reactions such as hydrocracking and isomerization,effectively controlling the selectivity for specific fractions.The mechanisms of bifunctional catalysts were introduced,and the reaction performances reported in existing studies were compared.The synthetic strategy and structure-performance relationship in different catalytic systems were emphasized,including the size effect,pore structure and acidity control of zeolites,as well as promoter effect.An outlook on the application of bifunctional catalysts for direct synthesis of jet fuel from FTS was provided.

关键词

费托合成/航空煤油/双功能催化剂

Key words

Fischer-Tropsch synthesis/jet fuel/bifunctional catalysts

分类

化学工程

引用本文复制引用

刘津旭,吕帅帅,李红伟,周秋明,牛丛丛,徐润,李新刚..费托合成直接制航空煤油中双功能催化剂的研究进展[J].低碳化学与化工,2025,50(1):13-19,7.

基金项目

国家重点研发计划(2021YFE0191200). (2021YFE0191200)

低碳化学与化工

OA北大核心

1001-9219

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