液晶与显示2025，Vol.40Issue(1)：153-170,18.DOI:10.37188/CJLCD.2024-0264
二维α-磷酸锆液晶的相变及调控研究进展
Advances of phase transitions and regulation of two-dimensional α-zirconium phosphate liquid crystals
摘要
Abstract
With the advancement of material synthesis methods,a wide range of two-dimensional(2D)materials with exceptional properties,such as graphene,boron nitride,MXenes,and black phosphorus,have emerged,making the study of 2D material colloidal liquid crystals and their self-assembly behaviors increasingly important.Alpha-zirconium phosphate(α-ZrP),a typical layered material,has significant applications in fields such as mechanical reinforcement,barrier enhancement,flame retardancy,corrosion resistance,catalysis,environmental protection,energy,and medicine.Due to the ability of α-ZrP crystals to be exfoliated into monolayer nanosheets through various chemical methods,and its advantages of controllable synthesis,low polydispersity,and stable physicochemical properties,α-ZrP has been systematically studied as a physical template for research on 2D material colloidal liquid crystals.This article provides a detailed discussion on the synthesis methods,exfoliation techniques,self-assembly into liquid crystals,and regulatory strategies of α-ZrP.The main factors influencing the liquid crystal phase transitions of α-ZrP include the aspect ratio,polydispersity,temperature,ion concentration,electric field,magnetic field,and spherical particle mixing.Changes in these regulatory conditions lead to diverse phase behaviors and phase structures.This article also explores the potential applications of α-ZrP as a next-generation functional material and highlights the importance of research on its liquid crystal phase transitions as a significant reference for the study of 2D material colloidal liquid crystals and the assembly of 2D materials into macroscopic structures.关键词
α-磷酸锆/溶致液晶/自组装/二维材料Key words
zirconium phosphate/lyotropic liquid crystal/self-assemble/2D material引用本文复制引用
陈明风,黄斌,朱恺杰,成正东..二维α-磷酸锆液晶的相变及调控研究进展[J].液晶与显示,2025,40(1):153-170,18.基金项目
中央财政双一流项目(No.112100*1942223R1/005) Supported by Double First-class Project of Central Finance(No.112100*1942223R1/005) （No.112100*1942223R1/005）
