中国塑料2025，Vol.39Issue(1)：75-79,5.DOI:10.19491/j.issn.1001-9278.2025.01.012
有机-无机复合抗氧剂对聚苯硫醚结构与性能的影响
Effect of organic-inorganic compound antioxidant on structure and properties of polyphenylene sulfide
摘要
Abstract
An organic-inorganic compound antioxidant(GO-sHP)was prepared through chemical grafting of GA-80 into graphite oxide(GO)sheets.The resultant GO-sHP was melt-blended with polyphenylene sulfide(PPS)by using a mi-cro-twin-screw extruder.The structure and properties of the obtained PPS blends were intensively analyzed.The results indicate that GO-sHP showed high thermal stability and could well be melt-blended with PPS.GO-sHP exhibited good compatibility with the PPS matrix and could be uniformly dispersed in the matrix without any agglomerations.The intro-duction of GO-sHP could promote the crystallization of PPS to improve its crystallinity.As the GO-sHP content in-creased,the crystallization temperature of PPS increased and its supercooling degree decreased.The introduction of GO-sHP improved the thermal stability of PPS,and its heat resistance temperature index increased with an increase in the GO-sHP content.The addition of GA-80 improved the tensile fracture strength of PPS significantly.After thermal oxidation treatment,pure PPS presented a decrease in the tensile fracture strength by 4.1%.However,the PPS blend containing 0.3 wt%GO-sHP showed a decrease in the tensile fracture strength only by 2.4%.关键词
聚苯硫醚/氧化石墨/有机-无机复合抗氧化剂/结晶性能/抗氧化性Key words
polyphenylene sulfide/graphite oxide/organic-inorganic compound antioxidant/crystallization properties/oxidation resistance分类
化学化工引用本文复制引用
李荣南,殷茂力,刘峰,胡承功,邢剑..有机-无机复合抗氧剂对聚苯硫醚结构与性能的影响[J].中国塑料,2025,39(1):75-79,5.基金项目
国家自然科学基金(52203114) （52203114）
