材料工程2025,Vol.53Issue(2):96-105,10.DOI:10.11868/j.issn.1001-4381.2022.001048
可充电镁硫二次电池研究进展
Research progress in rechargeable magnesium-sulfur secondary batteries
摘要
Abstract
Emerging energy storage technologies must meet the requirements of low cost,reasonable safety,rich natural resources and high energy density.The rechargeable magnesium sulfur(Mg-S)battery has the advantages of high energy density,high safety,low cost,and so on.However,its performance is limited by self-discharge,rapid capacity loss,magnesium anode passivation,and low sulfur utilization.The recent advances in Mg-S battery research,focusing on the advances in non-nucleophilic electrolytes,anodes,and cathodes,summarizing electrolytes that can facilitate reversible deposition and dissolution of magnesium ions,and maintaining compatibility with sulfur cathodes and other battery components are reviewed in this paper.In addition,the current challenges of magnesium-sulfur batteries are discussed in the context of research trends,such as the dissolution and diffusion of sulfides and the slow reaction kinetics of Mg-S batteries,as well as recommendations for the future,such as doping MOFs with different elements and exploring the reaction mechanism of the batteries.关键词
镁硫电池/电解质/硫正极/多硫化物Key words
Mg-S battery/electrolyte/sulfur cathode/polysulfide分类
通用工业技术引用本文复制引用
杜文涛,闫晓燕,刘宝胜,赵新新,张晓华,王明菊..可充电镁硫二次电池研究进展[J].材料工程,2025,53(2):96-105,10.基金项目
山西省基础研究计划面上项目(202203021221157) (202203021221157)
山西省重点研发计划项目(202102050201003) (202102050201003)
国家自然科学基金面上项目(52071227) (52071227)
山西省基础研究计划青年科学研究项目(20210302124225) (20210302124225)
太原科技大学研究生教育创新项目(SY2023002) (SY2023002)