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煤基石脑油裂解制丙烯聚合小试性能研究

杜正平 李磊 李红俊 申宏鹏 罗秉伟

合成材料老化与应用2025,Vol.54Issue(1):21-23,3.
合成材料老化与应用2025,Vol.54Issue(1):21-23,3.

煤基石脑油裂解制丙烯聚合小试性能研究

Research on the Performance of Coal-based Naphtha Pyrolysis to Propylene Polymerization

杜正平 1李磊 1李红俊 2申宏鹏 1罗秉伟1

作者信息

  • 1. 国家能源集团宁夏煤业有限责任公司,宁夏银川 750001
  • 2. 宁夏计量质量检验检测研究院,宁夏银川 750001
  • 折叠

摘要

Abstract

In this paper,the polymerization behavior of propylene synthesized from coal-based naphtha cracking to propylene and methanol to olefins under different polymerization conditions was compared and analyzed,the experimental results show that:With the increase of standing time,the activity of Propylene 1 polymerization reaction gradually decreased,and even non-polymerization appeared,however,there was no significant change in the activity of Propylene 2 polymerization;The same catalyst was used to catalyze the polymerization of propylene,and the activity of Propylene 1 polymerization reaction,melt index and isotactic index of polymerization products were lower than those of Propylene 2;Different catalysts were used to catalyze the propylene polymerization reaction,and the change trend of Propylene 1 and Propylene 2 was consistent;Increasing the dosage of triethyl aluminum within a certain range can significantly improve the polymerization activity of propylene,but has no significant effect on the melt index and isotactic index of the polymerization products.

关键词

煤基石脑油裂解/丙烯聚合/活性/小试研究

Key words

coal-based naphtha cracking/propylene polymerization/activity/small-scale research

分类

化学化工

引用本文复制引用

杜正平,李磊,李红俊,申宏鹏,罗秉伟..煤基石脑油裂解制丙烯聚合小试性能研究[J].合成材料老化与应用,2025,54(1):21-23,3.

基金项目

2019年宁夏青年拔尖人才培养工程(宁人社发[2019]90号). (宁人社发[2019]90号)

合成材料老化与应用

1671-5381

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