含能材料2025，Vol.33Issue(2)：117-126,10.DOI:10.11943/CJEM2024267
TKX-50/AP复合微球的制备及性能
Preparation and Properties of TKX-50/AP Composite Microspheres
摘要
Abstract
To obtain new energetic materials with high energy,low sensitivity and liable storage,TKX-50/AP composite micro-spheres were prepared by spray drying method.The effects of different feed rates on the morphology of composite microspheres were investigated,and the optimum process conditions were obtained.The morphology and crystal form of the samples were characterized by scanning electron microscope,X-ray diffractometer and Fourier infrared spectrometer.The thermal decomposi-tion performance,impact sensitivity and hygroscopicity of the microspheres were also studied.Results show that the samples are spherical particles with sphericity of Φ=96.40%and d50=1.33 μm at the feed rate of 3.6 mL·min-1.The crystal structure is differ-ent from that of mechanical mixing of TKX-50 and AP.The thermal decomposition activation energy is 184.43 kJ·mol-1,the char-acteristic drop is 50.1 cm,and the hygroscopicity is 37%lower than that of the physical mixing,showing excellent safety perfor-mance.关键词
TKX-50/AP复合微球/喷雾干燥法/吸湿性/机械感度Key words
TKX-50/AP composite microspheres/spray drying method/moisture absorption/mechanic sensitivity分类
军事科技引用本文复制引用
王新飞,杨俊清,赵含笑,王挺辉,郝嘎子,肖磊,姜炜..TKX-50/AP复合微球的制备及性能[J].含能材料,2025,33(2):117-126,10.基金项目
国家自然科学基金联合基金(U2141202) Grant support:National Natural Science Foundation of China Joint Fund(No.U2141202) （U2141202）
