含能材料2025,Vol.33Issue(2):198-211,14.DOI:10.11943/CJEM2024243
含能聚醚黏合剂的柔性链结构设计的研究进展
Research Progress on the Design of Flexible Chain Structures for Energetic Polyether Binders
彭肖玥 1王宇 2孙倩 3王亚 3李雅楠 1郑文芳1
作者信息
- 1. 南京理工大学安全科学与工程学院,江苏 南京 210094
- 2. 上海新力动力设备研究所,上海 201109
- 3. 中国爆破器材行业协会,北京 100089
- 折叠
摘要
Abstract
Energetic polyether binders,as the backbone and matrix of propellants,are the basis to improve the energy levels,me-chanical properties,and processing properties of propellants.However,the polar energetic groups in polyethers hinder the movement of molecular chains and reduce the flexibility of polymer chains,leading to a decrease in mechanical properties and restricting the development of energetic solid propellants.Copolymerization modification of energetic polyethers and introduc-tion of flexible structural units to improve flexibility are effective methods to obtain polyethers with diverse structures and adjust-able properties.This paper summarizes different types of flexible chain segments introduced into energetic polyethers in recent years,and discusses from the perspectives of main-chain flexible chain segments and side-chain flexible chain segments to ex-plain their effects on the mechanical properties and processing performance of energetic polyether binders.Future design of the flexible chain structure of energetic polyether binders is also discussed,which will provide a direction for the design and devel-opment of new types of energetic binders.关键词
聚醚类黏合剂/高分子链/柔顺性/固体推进剂Key words
polyether binders/polymer chain/mechanical property/solid propellant分类
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彭肖玥,王宇,孙倩,王亚,李雅楠,郑文芳..含能聚醚黏合剂的柔性链结构设计的研究进展[J].含能材料,2025,33(2):198-211,14.