石油化工2025，Vol.54Issue(2)：179-184,6.DOI:10.3969/j.issn.1000-8144.2025.02.005
超高金属负载量NiMoW/SiO2催化剂的制备及其柴油加氢性能
Preparation of NiMoW/SiO2 catalyst with ultra-high metal loading and their diesel hydrogenation performance
孙利民 1李宇航 2李若愚 1何砺锋 2刘宾 2柴永明2
作者信息
- 1. 中国石油石油化工研究院 兰州化工研究中心,甘肃 兰州 730060
- 2. 中国石油大学(华东)化学化工学院,山东 青岛 266580
- 折叠
摘要
Abstract
The NiMoW/SiO2 catalyst with ultra-high metal loading was prepared by the incipient wetness impregnation method.The structure of the catalyst was characterized by N2 adsorption-desorption,XRD,XPS,and HRTEM,and the effect of metal loading on the deep diesel hydrogenation performance of the catalyst was investigated.The experimental results show that with the increase in metal loading,the dispersion of the active components of the catalyst decreases gradually,along with the increased crystal length and stacking layers of the metal sulfides.When the metal loading is 50%(w),the catalyst has optimal active phase structure and distribution and shows the best diesel hydrogenation performance.The sulfur and nitrogen removal rate of diesel experiencing catalytic cracking after the reaction is more than 99.5%,showing a good industrial application prospect.关键词
高负载量/加氢脱硫/催化剂/柴油Key words
high loading/hydrodesulfurization/catalyst/diesel分类
化学化工引用本文复制引用
孙利民,李宇航,李若愚,何砺锋,刘宾,柴永明..超高金属负载量NiMoW/SiO2催化剂的制备及其柴油加氢性能[J].石油化工,2025,54(2):179-184,6.
