井冈山大学学报（自然科学版）2025，Vol.46Issue(1)：45-50,6.DOI:10.3969/j.issn.1674-8085.2025.01.007
高强度且快速自修复双交联结构聚乙烯醇水凝胶的制备及其自修复性能研究
PREPARATION AND SELF-HEALING PROPERTIES OF HIGH-STRENGTH,RAPID SELF-HEALING DOUBLE-CROSSLINKED STRUCTURAL POLYVINYL ALCOHOL HYDROGEL
摘要
Abstract
Aiming to constructing a kind of high-strength and rapid self-healing hydrogel.Here,a hydrogen bond between PVA and starch molecules is used as the first physical cross-linking network,and the dynamic borate ester bond between PVA and boric acid molecules is used as the second chemical cross-linking network to form a dual cross-linked structure of AR/PVA-B hydrogel.The AR/PVA-B hydrogel shows outstanding mechanical properties(Breaking elongation of 631.2%,Maximum stress of 24.6 kPa)and excellent self-healing performance(self-healing efficiency of 94.5%under no external stimulation conditions at room temperature within 5 minutes).In addition,the self-healing hydrogel also shows excellent recasting performance.This study provides theoretical support and exploration for the high-strength and rapid self-healing performance of PVA hydrogel in electronic skin applications.关键词
聚乙烯醇水凝胶/双网络结构/高强度/自修复性能Key words
PVA hydrogel/dual network structure/high strength/self-healing引用本文复制引用
曾龙华,张亿丹,尧静萍,钟程萱,谢舒勇,戴胜平,刘诚..高强度且快速自修复双交联结构聚乙烯醇水凝胶的制备及其自修复性能研究[J].井冈山大学学报（自然科学版）,2025,46(1):45-50,6.基金项目
国家自然科学基金项目(22365019) （22365019）
江西省自然科学基金项目(20224BAB214031,20224BAB204008) （20224BAB214031,20224BAB204008）
江西省教育厅科技计划项目(GJJ2201652,GJJ2201648) （GJJ2201652,GJJ2201648）
