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典型焦煤在热解和成焦过程中的流动性和形貌变化规律

王旭 刘福军 裴贤丰 赵奇 甘秀石 候士彬 周琦 王岩 武吉 王超 朱庆庙 赵振兴

煤质技术2025,Vol.40Issue(1):37-43,7.
煤质技术2025,Vol.40Issue(1):37-43,7.DOI:10.3969/j.issn.1007-7677.2025.01.006

典型焦煤在热解和成焦过程中的流动性和形貌变化规律

Changes in the quality characteristics of typical coking coal during pyrolysis and coking processes

王旭 1刘福军 1裴贤丰 2赵奇 2甘秀石 1候士彬 3周琦 2王岩 2武吉 1王超 1朱庆庙 1赵振兴1

作者信息

  • 1. 海洋装备用金属材料及其应用国家重点实验室,辽宁 鞍山 114009||鞍钢集团钢铁研究院,辽宁 鞍山 114009
  • 2. 煤炭科学技术研究院有限公司,北京 100013||国家能源煤炭高效利用与节能减排技术装备重点实验室,北京 100013||中国煤科低碳技术研究院,北京 100013
  • 3. 鞍钢股份炼焦总厂,辽宁 鞍山 114021
  • 折叠

摘要

Abstract

Studying the transformation law of the coking coal during pyrolysis and the reflectance and the morphology in coking processes is of great significance for revealing the coking mechanism of coking coal.The differences in vit-rinite reflectance,distribution patterns,and microscopic composition of four types of coking coal were studied using coal petrology analysis methods.The effect of pyrolysis temperature on the flowability of coking coal plastie mass was studied using the gieseler fluidity.The influence of pyrolysis temperature on the surface morphology of pyrolysis solid products was studied using crucible coke experiments and electron microscopy.The results indicate that there are sig-nificant differences in the basic coal quality characteristics of the four types of coking coal,and the correlation be-tween conventional indicators and coke quality is not very significant;JM-4 has the lowest content of vitrinite and it is classified as a low vitrinite coal along with JM-2,JM-1 and JM-3 belong to the mesoscopic coal group;the flow-ability of the corresponding plastie mass in JM-2 and JM-3 increases rapidly with increasing temperature,and the flowability of the plastie mass is basically the same,while the flowability of JM-1 is the smallest at the same tempera-ture;as the pyrolysis temperature increases,the porosity of the pyrolysis products obtained from JM-1 shows a trend of first increasing and then decreasing,with the highest particle porosity corresponding to the maximum flowability of the gel body.

关键词

典型焦煤/镜质体反射率/胶质体流动性/表面形貌/热解/成焦过程/孔隙率

Key words

typical coking coal/vitrinite reflectance/colloidal flowability/surface morphology/pyrolysis/coke forming process/porosity

分类

化学工程

引用本文复制引用

王旭,刘福军,裴贤丰,赵奇,甘秀石,候士彬,周琦,王岩,武吉,王超,朱庆庙,赵振兴..典型焦煤在热解和成焦过程中的流动性和形貌变化规律[J].煤质技术,2025,40(1):37-43,7.

基金项目

鞍钢股份有限公司B级科研课题基金资助项目(L2022A1C20303) (L2022A1C20303)

煤质技术

1007-7677

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