β相氧化镓p型导电研究进展OA北大核心
Research Progress on p-Type Conduction of β Phase Gallium Oxide
β相氧化镓(β-Ga2O3)具有超宽带隙、高击穿电场和容易制备等优势,是功率器件的理想半导体材料.但由于β-Ga2O3价带顶能级位置低、能带色散关系平坦,其p型掺杂目前仍具有挑战性,限制了p-n结及双极性晶体管的开发.利用尺寸效应、缺陷调控、非平衡动力学及固溶提升价带顶能级等方案是目前实现β-Ga2O3 p型掺杂的主要策略.对于β-Ga2O3 p-n同质结和异质结,提高晶体质量、减少界面缺陷态是优化器件性能的关键问题.本文针对β-Ga2O3的p型导电问题,系统阐述了β-Ga2O3电子结构,实验表征及理论计算掺杂能级方法,p型掺杂困难原因,以及改进p型掺杂的突破性研究进展.最后简单介绍了β-Ga2O3 p-n同质结和异质结器件的相关工作.利用复合缺陷调控、非平衡动力学、固溶等方案,以及不同方案的协同实现体相β-Ga2O3的p型掺杂仍需要深入探索,p-n同质及异质结的器件性能需要进一步优化.
β phase gallium oxide(β-Ga2O3)is an ideal semiconductor material for power devices based on its ultra-wide bandgap,high breakdown electric field,and easy preparation.However,it is still challenging to realize p-type doping of the β-Ga2O3 because of its relatively low energy of valence band maximum(VBM)and flat band dispersion near the VBM,which limits the development of p-n junctions and bipolar transistors.The main strategies for the p-type doping of β-Ga2O3 in recent research are based on size effect,defect regulation,non-equilibrium dynamic process,and solid solution.For the β-Ga2O3 p-n homojunction and heterojunction,improving crystal quality and reducing the interface defect states are the key issues for optimizing devices'performances.This paper focuses on the p-type conductivity problem of β-Ga2O3,systematically reviews the electronic structure of β-Ga2O3,the experimental characterization and theoretical calculation method of doping levels,the reasons for p-type doping difficulty,and the breakthrough in research advancements for improving the p-type doping ofβ-Ga2O3.Finally,the relevant studies on the β-Ga2O3 p-n homojunction and heterojunction devices are briefly reviewed.It requires further exploration to realize p-type doping of bulk-phase β-Ga2O3 through complex-defect regulation,non-equilibrium dynamics,solid solution,and combining these schemes.The device performances of p-n homojunction and heterojunction also need further optimization.
查显弧;万玉喜;张道华
深圳平湖实验室,深圳 518111深圳平湖实验室,深圳 518111深圳平湖实验室,深圳 518111
物理学
β-Ga2O3p型导电电子结构受主能级固溶p-n结
β-Ga2O3p-type conductionelectronic structureacceptor levelsolid solutionp-n junction
《人工晶体学报》 2025 (2)
177-189,13
深圳平湖实验室项目(224120)
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