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人工无本底土壤培养实验下GDGTs的含量与分布特征

苗瑞 赵增浩 蔡泽园 刘旭 王欢业

岩矿测试2025,Vol.44Issue(2):316-329,14.
岩矿测试2025,Vol.44Issue(2):316-329,14.DOI:10.15898/j.ykcs.202405240120

人工无本底土壤培养实验下GDGTs的含量与分布特征

Abundance and Distribution of GDGTs in Incubated Artificial Soils with No Fossil Pool

苗瑞 1赵增浩 2蔡泽园 2刘旭 3王欢业2

作者信息

  • 1. 中国科学院地球环境研究所,黄土与第四纪地质国家重点实验室,陕西西安 710061||中国科学院大学,北京 100049
  • 2. 中国科学院地球环境研究所,黄土与第四纪地质国家重点实验室,陕西西安 710061
  • 3. 中国科学院地球环境研究所,黄土与第四纪地质国家重点实验室,陕西西安 710061||西安地球环境创新研究院,陕西西安 710061
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摘要

Abstract

Glycerol dialkyl glycerol tetraethers(GDGTs)derived from microorganisms are important tools for the study of paleoclimate changes.Incubation experiments are helpful to clarify the mechanisms for the responses of GDGTs to environmental parameters,and to test the reliability of related climatic proxies.However,previous GDGT incubation experiments were mainly conducted on a single strain or suffered from the influence of a background signal,hampering systematically understanding the precise response of this biomarker to environmental factors in a soil environment.In this paper,artificial soils without GDGTs were incubated under the same temperature but different soil water content(SWC)conditions.The results showed that:(1)The abundances of GDGTs were positively correlated with SWC,but phosphate buffer could inhibit the production of GDGTs;(2)The branched and isoprenoid tetraether index(BIT),a soil moisture proxy developed in natural soils,was not significantly correlated with SWC;(3)6-methyl brGDGTs were more abundant than 5-methyl brGDGTs,resulting in extremely high values of MBT'5ME and low MBT'.The results suggest that the BIT soil moisture proxy may indirectly(rather than directly)respond to SWC changes and confirm that high relative abundance of 6-methyl brGDGTs can affect the applicability of the MBT'5ME paleothermometer in soils.The BRIEF REPORT is available for this paper at http://www.ykcs.ac.cn/en/article/doi/10.15898/j.ykcs.202405240120.

关键词

GDGTs/培养实验/高分辨质谱/土壤湿度指标/温度指标

Key words

GDGTs/incubation experiment/high resolution mass spectrometry/soil moisture proxy/temperature proxy

分类

天文与地球科学

引用本文复制引用

苗瑞,赵增浩,蔡泽园,刘旭,王欢业..人工无本底土壤培养实验下GDGTs的含量与分布特征[J].岩矿测试,2025,44(2):316-329,14.

基金项目

国家自然科学基金项目(42122021) (42122021)

国家重点研发计划项目(2023YFF0804300) (2023YFF0804300)

中国科学院青年创新促进会会员项目(2019403) (2019403)

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