中南大学学报（自然科学版）2025，Vol.56Issue(2)：435-442,8.DOI:10.11817/j.issn.1672-7207.2025.02.003
无负极锂金属电池的存储性能
Storage performance of anode-free lithium metal batteries
摘要
Abstract
Cu||NCM712 pouch batteries were fabricated as the research model.Combined with SEM,XRD,cryo-TEM and charge-discharge tests,the irreversible capacity loss and the reversible capacity loss during the storage process of anode-free lithium metal batteries(AF-LMBs)were evaluated qualitatively and quantitatively.The results show that the initial charging state has no significant effect on the storage performance(capacity retention rate and capacity recovery rate)of the Cu||NCM712 battery at 25℃,and the increase of storage temperature will aggravate the self discharge of the fully charged battery,resulting in an increase of the reversible capacity loss of the battery.Meanwhile,compared with the chemical corrosion between lithium metal and electrolyte,the galvanic corrosion between lithium metal and Cu collector is the main factor causing irreversible capacity loss of Cu||NCM712 battery.关键词
无负极锂金属电池/可逆容量损失/不可逆容量损失/存储性能Key words
anode-free lithium metal batteries/reversible capacity loss/irreversible capacity loss/storage performance分类
信息技术与安全科学引用本文复制引用
郭姿珠,张睿,孙旦,王海燕,黄小兵,唐有根..无负极锂金属电池的存储性能[J].中南大学学报（自然科学版）,2025,56(2):435-442,8.基金项目
国家自然科学基金资助项目(22272205) （22272205）
国家资助博士后研究人员项目(GZC20233152) （GZC20233152）
湖南省普通高等学校科技创新团队支持项目(2023)(Project(22272205)supported by the National Natural Science Foundation of China （2023）
Project(GZC20233152)supported by the Postdoctoral Felloship Program of CPSF （GZC20233152）
Project(2023)supported by the Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province) （2023）
