发光学报2025，Vol.46Issue(3)：508-518,11.DOI:10.37188/CJL.20240252
光辅助非水系锂氧气电池:光电阴极的制备与展望
Photo-assisted Non-aqueous Lithium-oxygen Batteries:Preparation and Prospect of Photocathode Materials
摘要
Abstract
Photo-assisted Li-O2 batteries(LOBs)have remained a prominent and growing field over the past sever-al years.However,the presence of slow oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),large charging and discharging overpotentials,and unstable cycle life lead to low energy efficiency,thus limiting their commercial application.The rational design and synthesis of photocathode materials are effective ways to solve the above existing problems of photo-assisted LOB systems.Herein,the recent advances in the design and prepara-tion of photocathode materials for photo-assisted LOBs were summarized in this review.First,we summarize the ba-sic principles and comprehension of the reaction mechanism for photo-assisted LOBs.The second part introduces the latest research progress on photocathode materials.The third section describes the relationship between the structure-properties and electrochemistry of different photocathodes.In addition,attempts to construct efficient photocathode materials for photo-assisted LOBs through vacancy engineering,localized surface plasmon resonance(LSPR),and heterojunction engineering are mainly discussed.Finally,a discussion of attempts to construct efficient photocathode materials using other approaches is also presented.This work will motivate the preparation of stable and efficient pho-tocathode materials for photo-assisted LOBs and aims to promote the commercial application of rechargeable photo-as-sisted LOBs energy storage.关键词
光辅助/锂氧气电池/光催化/电极设计Key words
photo-assisted/lithium-oxygen battery/photocatalysis/electrode design分类
化学化工引用本文复制引用
薛志超,蒋四海,茹颖懿,李洁,李强,孙红..光辅助非水系锂氧气电池:光电阴极的制备与展望[J].发光学报,2025,46(3):508-518,11.基金项目
国家自然科学基金(52476083) （52476083）
辽宁省教育厅(LJ242410153025,JYTZD202316,LJ222410153070) Supported by National Natural Science Foundation of China(52476083) （LJ242410153025,JYTZD202316,LJ222410153070）
Educational Commission of Liaoning Province,China(LJ242410153025,JYTZD202316,LJ222410153070) （LJ242410153025,JYTZD202316,LJ222410153070）
