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钙化钒液萃取除杂工艺研究

汪劲鹏 叶露

钢铁钒钛2025,Vol.46Issue(1):20-24,33,6.
钢铁钒钛2025,Vol.46Issue(1):20-24,33,6.DOI:10.7513/j.issn.1004-7638.2025.01.003

钙化钒液萃取除杂工艺研究

Study on the impurities removal process of calcified vanadium liquid by extraction process

汪劲鹏 1叶露1

作者信息

  • 1. 钒钛资源综合利用国家重点实验室,攀钢集团研究院有限公司,四川攀枝花 617000
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摘要

Abstract

The acidic calcified vanadium solution from Pangang Xichang Vanadium Plant was the re-search object in this study.In response to its characteristics of low acidity,high vanadium content,and difficulty in impurities removal,an extraction process was adopted to specifically remove Mn2+,Ca2+and Fe3+cations.The main influencing factors of the extraction process were investigated.And the op-timal extraction parameters were determined.The organic phase ratio was 20%P204+80%260# solvent oil with a saponification rate of 100%using ammonium hydroxide.The extractant ratio was O/A=2∶1 at the initial pH of vanadium solution of 2.9 for 5 minutes.Under the above conditions,the single stage extraction rate of Mn and Ca reach over 98%.After extraction,the Mn content drops to around 0.05 g/L,Ca,Fe and Al leves are below 0.1 g/L in acidic vanadium solution.

关键词

酸性钒液/钙化提钒/萃取除杂/除锰

Key words

acid vanadium solution/vanadium extraction by calcification/impurities removal using ex-traction process/manganese removal

分类

矿业与冶金

引用本文复制引用

汪劲鹏,叶露..钙化钒液萃取除杂工艺研究[J].钢铁钒钛,2025,46(1):20-24,33,6.

钢铁钒钛

OA北大核心

1004-7638

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