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h-BN对超低介电损耗COC/h-BN复合材料导热性能、介电性能的影响

钱康乐 彭海益 何代华 姚晓刚 林慧兴

有色金属材料与工程2025,Vol.46Issue(1):67-74,8.
有色金属材料与工程2025,Vol.46Issue(1):67-74,8.DOI:10.13258/j.cnki.nmme.20240318001

h-BN对超低介电损耗COC/h-BN复合材料导热性能、介电性能的影响

Effect of h-BN on the thermal conductivity and dielectric properties of ultra-low dielectric loss COC/h-BN composites

钱康乐 1彭海益 2何代华 3姚晓刚 2林慧兴2

作者信息

  • 1. 上海理工大学 材料与化学学院,上海 200093||中国科学院 上海硅酸盐研究所,上海 201899
  • 2. 中国科学院 上海硅酸盐研究所,上海 201899
  • 3. 上海理工大学 材料与化学学院,上海 200093
  • 折叠

摘要

Abstract

The microwave composites with high thermal conductivity of cycloolefin copolymer(COC)/hexagonal boron nitride(h-BN)(COC/h-BN)with different volume fractions(10%-30%)and different particle sizes(10,25 μm)h-BN were prepared by using twin-screw granulation and hot pressing technology.The microstructure,microwave dielectric properties and thermal properties of the composites were studied by scanning electron microscopy,vector network analyzer and thermal dilatometer.The results show that the COC/h-BN-25 composite has higher density and thermal conductivity than that of the COC/h-BN-10 composite.When the volume fraction of h-BN is 30%,the thermal conductivities of the COC/h-BN-25 composite reaches 0.766 W/(m·K)in the X/Y direction and 1.204 W/(m·K)in Z direction,with low dielectric loss.

关键词

粒径/六方氮化硼/导热性能/介电性能/环烯烃类共聚物

Key words

particle size/hexagonal boron nitride/thermal conductivity/dielectric property/cycloolefin copolymer

分类

通用工业技术

引用本文复制引用

钱康乐,彭海益,何代华,姚晓刚,林慧兴..h-BN对超低介电损耗COC/h-BN复合材料导热性能、介电性能的影响[J].有色金属材料与工程,2025,46(1):67-74,8.

基金项目

国家自然科学基金资助项目(52302122) (52302122)

有色金属材料与工程

2096-2983

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