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镍质量分数对B30合金耐腐蚀性能的影响

杜永豪 陈小红 周洪雷 付少利 刘平

有色金属材料与工程2025,Vol.46Issue(1):90-97,8.
有色金属材料与工程2025,Vol.46Issue(1):90-97,8.DOI:10.13258/j.cnki.nmme.20240228001

镍质量分数对B30合金耐腐蚀性能的影响

Effect of Ni mass fractionon on the corrosion resistance of B30 alloy

杜永豪 1陈小红 1周洪雷 1付少利 1刘平1

作者信息

  • 1. 上海理工大学 材料与化学学院,上海 200093
  • 折叠

摘要

Abstract

The simulated seawater erosion corrosion experiments were carried out on B30 alloy with different nickel mass fractions.The effects of Ni mass fraction on the microstructures and corrosion resistance of B30 alloy were analyzed by optical microscope,scanning electron microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,and electrochemical impedance spectroscopy.The results show that numerous twins are observed in the of B30 alloy with different Ni mass fraction after annealing.With the increase of nickel mass fraction,the tensile strength and Vickers hardness of B30 alloy increase,the surface corrosion product film becomes denser and the corrosion resistance improves.The corrosion product film of B30 alloy surface is composed of Cu2O and Cu2(OH)3Cl.When the mass fraction of Ni is 33%,the inner corrosion product film on the surface of the B30 alloy has the most positive self-corrosion potential,the smallest self-corrosion current density,the maximum electrochemical impedance of the inner corrosion product film,which is 16 481.28 Ω/cm2,indicating optimal corrosion resistance.

关键词

B30合金/冲刷腐蚀/腐蚀产物膜/电化学阻抗/耐腐蚀性能

Key words

B30 alloy/erosion corrosion/corrosion product film/electrochemical impedance/corrosion resistance

分类

矿业与冶金

引用本文复制引用

杜永豪,陈小红,周洪雷,付少利,刘平..镍质量分数对B30合金耐腐蚀性能的影响[J].有色金属材料与工程,2025,46(1):90-97,8.

基金项目

国家自然科学基金资助项目(51201107) (51201107)

有色金属材料与工程

2096-2983

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