有色金属材料与工程2025,Vol.46Issue(1):90-97,8.DOI:10.13258/j.cnki.nmme.20240228001
镍质量分数对B30合金耐腐蚀性能的影响
Effect of Ni mass fractionon on the corrosion resistance of B30 alloy
摘要
Abstract
The simulated seawater erosion corrosion experiments were carried out on B30 alloy with different nickel mass fractions.The effects of Ni mass fraction on the microstructures and corrosion resistance of B30 alloy were analyzed by optical microscope,scanning electron microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,and electrochemical impedance spectroscopy.The results show that numerous twins are observed in the of B30 alloy with different Ni mass fraction after annealing.With the increase of nickel mass fraction,the tensile strength and Vickers hardness of B30 alloy increase,the surface corrosion product film becomes denser and the corrosion resistance improves.The corrosion product film of B30 alloy surface is composed of Cu2O and Cu2(OH)3Cl.When the mass fraction of Ni is 33%,the inner corrosion product film on the surface of the B30 alloy has the most positive self-corrosion potential,the smallest self-corrosion current density,the maximum electrochemical impedance of the inner corrosion product film,which is 16 481.28 Ω/cm2,indicating optimal corrosion resistance.关键词
B30合金/冲刷腐蚀/腐蚀产物膜/电化学阻抗/耐腐蚀性能Key words
B30 alloy/erosion corrosion/corrosion product film/electrochemical impedance/corrosion resistance分类
矿业与冶金引用本文复制引用
杜永豪,陈小红,周洪雷,付少利,刘平..镍质量分数对B30合金耐腐蚀性能的影响[J].有色金属材料与工程,2025,46(1):90-97,8.基金项目
国家自然科学基金资助项目(51201107) (51201107)