空天防御2025，Vol.8Issue(1)：109-116,8.
PSAN燃气发生剂配方设计及性能研究
Formulation Design and Performance Study of PSAN-Based Gas Generating Agent
摘要
Abstract
To develop gas-generating agents which are clean,high production,and have a low residue rate,the formulation screening and preparation process of gas-generating agents using PSAN were investigated.The combustion temperature,gas production,residue rate,flame morphology and safety of the formulation were tested.The results show that the optimum ratio of oxidant,binder and plasticizer in the formulation is respectively 40%,30%and 30%.The combustion temperatures of PSAN/PBT/A3,PSAN/PBT/BuNENA and PSAN/PET/A3 are respectively 1 441 K,1 611 K and 1 309 K,and the gas production is 55.2 mol·kg-1,49.3 mol·kg-1 and 57.7 mol·kg-1.The condensed phase contents are respectively 6.75%,7.25%and 6.57%.The combustion flame of PSAN/PBT/A3 is the brightest.The flame brightness of PSAN/PBT/BuNENA decreases with a large carbon smoke emission,while the combustion of PSAN/PET/A3 produces a large amount of carbon smoke and contains only a weak flame.The impact sensitivities of PSAN/PBT/A3,PSAN/PBT/BuNENA and PSAN/PET/A3 gas generating agents are respectively 34.4,21.6 and 35.8 cm,and the friction sensitivities are low.关键词
相稳定硝酸铵/燃气发生剂/成气量/燃烧性能Key words
phase stabilized ammonium nitrate(PSAN)/gas generating agent/gas generating capacity/combustion performance分类
化学化工引用本文复制引用
李波标,赵佳钏,姚张奕,陈国良,李家泰,王鹏飞,刘林林..PSAN燃气发生剂配方设计及性能研究[J].空天防御,2025,8(1):109-116,8.基金项目
国家自然科学基金资助项目(51976175) （51976175）
中国航天科技集团有限公司上海航天科技创新基金资助项目(SAST2022-008) （SAST2022-008）
