云南化工2025，Vol.52Issue(3)：42-45,4.DOI:10.3969/j.issn.1004-275X.2025.03.09
PVA/(AA-co-AM)/LiTFSI复合离子导电水凝胶的制备及其性能研究
Preparation and Properties Testing of PVA/(AA-co-AM)/LiTFSI Composite Conductive Hydrogel
摘要
Abstract
In this work,a series of PVA/(AA-co-AM)/LiTFSI composite ion conductive hydrogelsbased on PVA,AA,AM and LiTFSIwere pre-pared by free radical polymerization,using potassium persulfate(KPS)as the high-efficiency initiator,and theswelling properties,thermal stabili-ty,mechanical propertiesand electrical properties of composite conductive hydrogels were studied.The results showed thatthe amount of polyvinyl alcohol had little influence on the thermal stability of thePVA/(AA-co-AM)/LiTFSI composite ionic conductive hydrogel,and the thermal de-composition temperature of the prepared hydrogelreached about 210℃,indicating that it had excellent thermal stability,but the swelling proper-ties,tensile properties and electrical properties increased first and then decreased with the increase of the amount of PVA.The comprehensive performance of sample P2 was the best,the swelling degree was94.29g/g,the elongation reached3108%,the resistance and conductivity were 7.50 Ω and10.6×10-3 S/m,respectively.关键词
导电水凝胶/锂离子/聚乙烯醇/氢键/溶胀度/电导率Key words
Conductive Hydrogel/Lithium Ion/Polyvinyl Alcohol/Hydrogen Bond/Swelling Degree/Conductivity分类
化学工程引用本文复制引用
于思瀚,肖幸,徐永明,薛晨阳,刘铭航,颜娇娇..PVA/(AA-co-AM)/LiTFSI复合离子导电水凝胶的制备及其性能研究[J].云南化工,2025,52(3):42-45,4.基金项目
湖南省教育厅资助科研项目(22C0624)、湖南省大学生创新训练计划一般项目(S202411528146). （22C0624）
