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表面改性Sb2O3对阻燃ABS/DBDPE/Sb2O3复合材料性能的影响

武本泽 李滨 雷园 黄绍军 吕汶骏 余传柏

中国塑料2025,Vol.39Issue(3):81-85,5.
中国塑料2025,Vol.39Issue(3):81-85,5.DOI:10.19491/j.issn.1001-9278.2025.03.015

表面改性Sb2O3对阻燃ABS/DBDPE/Sb2O3复合材料性能的影响

Effect of surface modified Sb2O3 on properties of flame-retardant ABS/DBDPE/Sb2O3 composites

武本泽 1李滨 1雷园 2黄绍军 2吕汶骏 2余传柏1

作者信息

  • 1. 桂林理工大学材料科学与工程学院,广西 桂林 541000
  • 2. 广西华锑科技有限公司,南宁 530000
  • 折叠

摘要

Abstract

Four surface modifiers,NDZ-201,GR-A118,KH-550 and DPAK,were used to modify Sb2O3 particles by wet ball milling.The structure and morphology of Sb2O3 before and after modification were characterized by FTIR,XRD and SEM.ABS/DBDPE/Sb2O3 composite was prepared by extrusion granulation and injection molding.The ef-fect of Sb2O3 modified by four surface modifiers of 2%on the composite properties was studied.The results show that Sb2O3 modified by four surface modifiers has a certain effect on the comprehensive properties of the composite.After sur-face modification,the machinability of the composite is obviously improved.After modification,good flame retardancy and thermal properties are maintained,and all vertical combustion passes the UL 94 V-0 grade.After modification,the mechanical properties are improved in different degrees,and the impact properties are improved obviously.The NDZ-201-modified composite presented impact strength of 46.99 kJ/m2.This result is 36.01%higher than the impact strength of unmodified composite.Moreover,the bending strength of the modified composite was also improved to some extent.NDZ-201 and DPAK exhibit good modification effect,facilitating an improvement in the machining and mechani-cal properties of composites.

关键词

丙烯腈-丁二烯-苯乙烯树脂/表面改性/三氧化二锑/阻燃性能

Key words

acrylonitrile-butadiene-styrene resin/surface modification modified/antimony trioxide/flame retardant property

分类

化学化工

引用本文复制引用

武本泽,李滨,雷园,黄绍军,吕汶骏,余传柏..表面改性Sb2O3对阻燃ABS/DBDPE/Sb2O3复合材料性能的影响[J].中国塑料,2025,39(3):81-85,5.

基金项目

南宁市重点研发项目(20221035、20231046) (20221035、20231046)

广西自然科学基金(2022GXNSFAA035566) (2022GXNSFAA035566)

广西重点研发计划项目(2023AB01274、2023AB02005) (2023AB01274、2023AB02005)

中国塑料

OA北大核心

1001-9278

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