大学化学2025，Vol.40Issue(2)：364-370,7.DOI:10.12461/PKU.DXHX202405159
可见光催化合成α-芳基环胺
Visible-Light Photoredox Synthesis of α-Aryl Cyclic Amines
摘要
Abstract
Photocatalytic synthesis has garnered significant attention over the past decade due to its mild reaction conditions,high efficiency,and excellent tolerance for functional groups,as well as its selectivity.While most undergraduate organic synthesis experiments focus on thermal reactions,radical photochemistry—an area at the forefront of research—has received less emphasis.The photoredox α-amino C(sp3)―H arylation reaction has been developed to produce valuable α-arylcycloalkylamines.This reaction is not only green and efficient,but also straightforward,making it accessible and comprehensible for students.Its inclusion in the curriculum enriches the content of photocatalytic reactions in basic organic chemistry courses and lays a solid foundation for further exploration in organic photochemistry.关键词
光催化/三级环胺/芳基化/有机化学实验Key words
Photoredox catalysis/Tertiary cyclic amines/Arylation/Organic chemistry laboratory分类
社会科学引用本文复制引用
徐文涛,马杰民,钟宇华..可见光催化合成α-芳基环胺[J].大学化学,2025,40(2):364-370,7.基金项目
南昌大学校级教学改革研究课题(NCUJGLX-2023-149-130) （NCUJGLX-2023-149-130）
南昌大学学位与研究生教育教学改革研究项目(NCUYJSJG-2023-069) （NCUYJSJG-2023-069）
