大学化学2025,Vol.40Issue(2):378-384,7.DOI:10.12461/PKU.DXHX202405156
光催化氧化绿色合成β-萘甲醛
Photocatalytic Oxidation for the Green Synthesis of β-Naphthaldehyde
摘要
Abstract
The oxidation of alcohols to aldehydes is a fundamental reaction in organic synthesis.Introducing this reaction as a core experiment in organic chemistry holds significant educational value,helping students grasp textbook concepts and familiarize themselves with essential laboratory techniques.This study presents the photocatalytic oxidation of β-naphthylmethanol,catalyzed by tetrabutylammonium decatungstate(TBADT)with oxygen as the oxidant,resulting in the successful synthesis of β-naphthaldehyde.The experiment is straightforward,yields high product output,and proceeds under mild conditions,making it highly suitable for undergraduate laboratory courses.关键词
光催化/氧化反应/TBADT/绿色化学Key words
Photocatalysis/Oxidation reaction/TBADT/Green chemistry分类
社会科学引用本文复制引用
郭冬冬,张永坡,殷丛丛,赵晋忠,王永强..光催化氧化绿色合成β-萘甲醛[J].大学化学,2025,40(2):378-384,7.基金项目
山西省高等学校教学改革创新项目(J20220280,J20220279,J2021226,J20230375,J20230379) (J20220280,J20220279,J2021226,J20230375,J20230379)
山西省教育科学"十四五"规划2022年度课题(GH-220372) (GH-220372)