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液-液相变吸收剂捕集二氧化碳研究进展

张履胜 王治红 柳青 李雪雯 谭仁敏

化工学报2025,Vol.76Issue(3):933-950,18.
化工学报2025,Vol.76Issue(3):933-950,18.DOI:10.11949/0438-1157.20240797

液-液相变吸收剂捕集二氧化碳研究进展

Research progress in carbon dioxide capture using liquid-liquid phase change absorbents

张履胜 1王治红 1柳青 2李雪雯 1谭仁敏1

作者信息

  • 1. 西南石油大学化学化工学院,四川 成都 610500
  • 2. 中石化广元天然气净化公司,四川 广元 638400
  • 折叠

摘要

Abstract

With the extensive use of fossil fuels,the emission of carbon dioxide(CO2)has increased year by year,causing global climate problems.To address this global issue,carbon capture,utilization,and storage(CCUS)is considered an important means to slow down CO2 emissions.Currently,organic amines are commonly used as CO2 absorbents,but their high regeneration energy consumption leads to high capture costs,which hinders the commercial deployment of CCUS.As a low-energy consumption absorbent,the liquid-liquid phase change absorbent,formulated with organic amines,functions as a solution capable of compensating for this deficiency.Liquid-liquid phase change absorbents are homogeneous under normal conditions,but phase change can be triggered when the polarity,hydrophilicity,or hydrogen bond strength changes,resulting in the formation of a CO2-lean phase and a CO2-rich phase.Only one phase enriched in CO2 is sent to regeneration,thus reducing regeneration energy consumption.This review summarizes the research progress of liquid-liquid phase change absorbents in recent years,and compares key aspects such as phase change characteristics,phase change mechanism,absorption loading,and regeneration energy consumption.Finally,combined with the demand for CO2 capture,other research contents that need to be improved are pointed out and future research directions are prospected.

关键词

二氧化碳捕集/有机胺/能耗/相变/吸收

Key words

CO2 capture/organic amines/energy consumption/phase change/absorption

分类

化学工程

引用本文复制引用

张履胜,王治红,柳青,李雪雯,谭仁敏..液-液相变吸收剂捕集二氧化碳研究进展[J].化工学报,2025,76(3):933-950,18.

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