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三元活性金属燃料Al/B/Mg和Al/B/MgH2的燃烧特性

程志鹏 夏语 罗一民 马腾 徐飞扬 张宇 吴星亮 徐森

含能材料2025,Vol.33Issue(3):246-255,10.
含能材料2025,Vol.33Issue(3):246-255,10.DOI:10.11943/CJEM2024100

三元活性金属燃料Al/B/Mg和Al/B/MgH2的燃烧特性

Combustion Characteristics of Ternary Reactive Metal Fuels Al/B/Mg and Al/B/MgH2

程志鹏 1夏语 1罗一民 1马腾 1徐飞扬 1张宇 1吴星亮 1徐森2

作者信息

  • 1. 南京理工大学化学与化工学院,江苏 南京 210094
  • 2. 南京理工大学化学与化工学院,江苏 南京 210094||国家民用爆破器材质量监督检验中心,江苏 南京 210094
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摘要

Abstract

To investigate the combustion characteristics of ternary active metal fuels Al/B/Mg(ABM)and Al/B/MgH2(ABM-H),the heat of combustion and minimum ignition energy were studied by using an oxygen bomb calorimeter and a Hartmann tube,respectively.The sub-transient process of flame propagation and the spatiotemporal distribution characteristics of temperature fields were determined by using a high-speed camera system and a high-speed infrared camera system.The results indicate that the calorific values of ABM and ABM-H are 34.1 and 32.2 MJ·kg-1,respectively,exhibiting increases of 14.4%and 8.1%over pure Al(29.8 MJ·kg-1).The minimum ignition energies of ABM,ABM-H,and Al are 160-170,100-110,and 20-30 mJ,re-spectively.Compared to pure Al,the combustion duration of ABM and ABM-H increase by 65.5%,34.5%and the peak flame propagation velocities increase by 12.6%,23.0%,respectively,at a mass concentration of 625 g·m-3.At a mass concentration of 500 g·m-3,ABM-H and ABM exhibit the largest peak flame propagation velocities by 45.05,38.7 m·s-1,and the maximum temperatures peak of flame surface by 1856,1717℃,respectively,where ABM-H shows a 7.6%improvement on temperatures peak of flame surface and a faster heating-rate compared to ABM.It suggests that the ABM and ABM-H formulations significantly reduce the explosion risk of the dust/air mixture,and significantly improving the combustion performance.ABM demonstrates su-perior thermal effects in calorific value and duration of combustion,whereas ABM-H exhibits higher reactivity in terms of mini-mum ignition energy,flame propagation speed,and temperature rise rate.

关键词

三元活性金属燃料/最小点火能/火焰传播特性/温度场分布

Key words

ternary reactive metallic fuels/minimum ignition energy/flame propagation characteristics/temperature field distribu-tion

分类

军事科技

引用本文复制引用

程志鹏,夏语,罗一民,马腾,徐飞扬,张宇,吴星亮,徐森..三元活性金属燃料Al/B/Mg和Al/B/MgH2的燃烧特性[J].含能材料,2025,33(3):246-255,10.

基金项目

国家自然科学基金(12272184) National Natural Science Foundation of China(No.12272184) (12272184)

含能材料

OA北大核心

1006-9941

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