生物质化学工程2025，Vol.59Issue(2)：1-8,8.DOI:10.3969/j.issn.1673-5854.2025.02.001
壳聚糖导电凝胶的制备及摩擦电性能研究
Preparation and Triboelectric Properties of Chitosan Conductive Gel
摘要
Abstract
Triboe nanogenerators(TENG)could effectively recover and utilize mechanical energy to generate electricity,which had great advantages in self-driven sensors.However,most triboelectric materials were petroleum-based,while the output performance of chitosan-based materials in biomass materials was low.Therefore,it was important to develop chitosan-based triboelectric materials with high output performance.In this study,phytate-chitosan/polyethylenimide(PA-CS/PEI)hydrogel was constructed using chitosan(CS),phytic acid(PA),and polyethylenei mine(PEI).This enabled the formation of a stable three-dimensional network structure with strong chemical cross-linking,and gold nanoparticles(AuNPs)was introduced to form a nanocomposite hydrogel system.When the mass fraction of chitosan in 25 mL chitosan-hydrochloric acid solution was 4％,the composite gel of PA-0.4％CS/PEI was prepared by adding 2 mL of 50％PA and 0.5 mL of 2％PEI,and its yield stress(1.6 MPa)was 4 times that of phytic acid chitosan gel(PA-2％CS,0.4 MPa).When the amount of AuNPs added in PA-CS/AuNPs/PEI hydrogel was 0.005 g,the conductivity of PA-0.4％CS/5AuNPs/PEI was 0.099 S/m,and the current value and power density were 11.1％and 23％higher than that of PA-CS/PEI,respectively,indicating that PA-CS/AuNPs/PEI had good electrical conductivity and triboelectric performance.This not only provided a new idea for energy harvesting,but also had a promising application prospect in flexible wearable sensors.关键词
壳聚糖/导电凝胶/摩擦电/柔性传感Key words
chitosan/conductive gel/triboelectricity/flexible sensor分类
化学工程引用本文复制引用
崔钰圆,杨恬欣,熊艳华,王汉琛,陈燕丹,卢麒麟..壳聚糖导电凝胶的制备及摩擦电性能研究[J].生物质化学工程,2025,59(2):1-8,8.基金项目
国家自然科学基金资助项目(32301529) （32301529）
福州市科技重大揭榜挂帅项目(2023-ZD-007) （2023-ZD-007）
福建省自然科学基金资助项目(2021J011034) （2021J011034）
闽江学院引进人才项目(MJY18010) （MJY18010）
