首页|期刊导航|高压物理学报|无机盐对硝酸铵溶解温度和膨化硝铵炸药爆炸性能的影响

无机盐对硝酸铵溶解温度和膨化硝铵炸药爆炸性能的影响OA北大核心

Influence of Inorganic Salts on the Dissolution Temperature of Ammonium Nitrate and the Explosive Performance of Expanded Ammonium Nitrate Explosives

中文摘要英文摘要

为了探究无机盐对硝酸铵溶解温度和膨化硝铵炸药爆炸性能的影响,分别添加不同质量分数(2%、4%和6%)的NaCl、KCl、NaNO3和KNO34种无机盐取代膨化硝铵炸药中的硝酸铵,测得了硝酸铵溶解温度和膨化硝铵炸药爆炸性能(爆速、猛度、做功能力)的影响.结果表明:添加无机盐质量分数为2%时,改良炸药较传统膨化硝铵配方炸药的溶解温度降低了 8~12 ℃;添加NaNO3和 KNO3的膨化硝铵炸药较传统配方炸药的爆速提高了 120~150 m/s,添加NaCl和KCl的膨化硝铵炸药降低了 150~850 m/s;添加NaNO3和KNO3的膨化硝铵炸药铅柱压缩量较传统配方增大了 0.62~1.90 mm,添加NaCl和KCl的铅柱压缩量降低了 0.06~2.55 mm;添加NaNO3和KCl的炸药超压峰值提高了 0.02~0.78 kPa,添加NaCl和KNO3的炸药超压峰值降低了 5.02~19.57 kPa.无机盐的质量分数每提高2%,溶解温度降低7~10℃,爆速降低100~300 m/s,铅柱压缩量缩小0.08~0.73 mm,超压峰值降低1.77~13.50 kPa.实际操作中,可以在膨化硝铵炸药中添加少量NaNO3,这样既有利于降低硝酸铵的溶解温度,同时有利于提高炸药的爆炸性能.

In order to explore the influence of inorganic salts on the dissolution temperature of ammonium nitrate and the explosive performance of expanded ammonium nitrate explosives,the inorganic salts of 2%,4%and 6%of NaCl,KCl,NaNO3 and KNO3 respectively were used to replace the ammonium nitrate content in the expanded ammonium nitrate explosives,and the explosion performance(including the detonation velocity,the fierceness,and the work ability were measured).The results show that when the mass fraction of inorganic salt is 2%,the dissolution temperature is 8 to 12 ℃ lower than that of the traditional puffed ammonium nitrate formula explosives;the expanded ammonium nitrate explosives with NaNO3 and KNO3 is 120-150 m/s higher than the traditional formula,and NaCl and KCl are reduced by 150-850 m/s;lead column compression of NaNO3 and KNO3 increased by 0.62-1.90 mm,and NaCl and KCl decreased by 0.06-2.55 mm;the peak overpressure of NaNO3 and KCl increased by 0.02-0.78 kPa,and NaCl and KNO3 inorganic salts decreased by 5.02-19.57 kPa.For every 2%increase in the mass fraction of inorganic salt substitution,the dissolution temperature decreases by 7 to 10 ℃;the detonation velocity decreases by 100 to 300 m/s;lead column compression decreases by 0.08 to 0.73 mm;and the peak overpressure decrease by 1.77 to 13.5 kPa.In practice,a small quantity of NaNO3 can be added to the expanded ammonium nitrate explosives,which is not only conducive to reducing the dissolution temperature of ammonium nitrate,but also enhances the explosive performance of explosives.

李炎;崔晓荣;李瑞;汪泉;胡明航;孙瑞;陈雅静

安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001||宏大民爆集团有限公司,广东 广州 510623安徽理工大学化工与爆破学院,安徽淮南 232001||宏大民爆集团有限公司,广东 广州 510623安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001安徽理工大学化工与爆破学院,安徽淮南 232001

力学

膨化硝铵炸药无机盐工业生产溶解温度爆炸性能

expanded ammonium nitrate explosiveinorganic saltindustrial productiondissolution temperatureexplosive performance

《高压物理学报》 2025 (4)

68-76,9

安徽省高等学校科学研究重点项目(2023AH051221)安徽省自然科学基金(2208085QA26)安徽理工大学博士引进人才基金项目

10.11858/gywlxb.20240914

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