中国石油大学学报（自然科学版）2025，Vol.49Issue(2)：256-264,9.DOI:10.3969/j.issn.1673-5005.2025.02.026
用于高性能双碳锂离子电容器的氮掺杂有序介孔碳的制备及其性能
Synthesis and properties of symmetrical Li-ion capacitor based on nitrogen-doped ordered mesoporous carbon
摘要
Abstract
The ordered mesoporous material(CMK-3)was doped with nitrogen by high temperature ammonification.The e-lectronic structure,nitrogen doping amount and type of the ordered mesoporous material(NC-T)were optimized by adjusting the calcination temperature.It is found that the NC-700 prepared at a calcination temperature of 700℃has 3.79%nitrogen doping,comprising 1.38%active pyridine nitrogen and 0.96%pyrrole nitrogen.When NC-700 is used as the LICs cathode material,the specific capacity of CMK-3 is increased by nearly 60%compared with the undoped ordered mesoporous carbon material.When NC-700 is used as both cathode and anode materials to form symmetrical LICs,the energy density of 225 W·h·kg-1 can be reached at a power density of 230 W·kg-1.关键词
锂离子电容器/有序介孔碳/氮掺杂Key words
Li-ion capacitor/ordered mesoporous carbon/nitrogen-doped分类
化学化工引用本文复制引用
房海秋,曹林芳,张燕,王斌..用于高性能双碳锂离子电容器的氮掺杂有序介孔碳的制备及其性能[J].中国石油大学学报（自然科学版）,2025,49(2):256-264,9.基金项目
国家重点研发计划项目(2023YFB42037) （2023YFB42037）
国家自然科学基金项目(22179145,22309206,21975287) （22179145,22309206,21975287）
山东省自然科学基金项目(ZR2020ZD08) （ZR2020ZD08）
泰山学者项目(tsqn20221117) （tsqn20221117）
中央高校基本科研基金项目(27RA2204027) （27RA2204027）
