化工环保2025,Vol.45Issue(2):302-307,6.DOI:10.3969/j.issn.1006-1878.2025.02.020
废酸中H2O2催化分解工艺研究
Catalytic decomposition of H2O2 in waste acid
沈伟 1李虎 1刘利娟 1张铁峰2
作者信息
- 1. 四川高绿平环境科技有限公司,四川 眉山 620000
- 2. 山东鲁新设计工程有限公司,山东 淄博 255000
- 折叠
摘要
Abstract
In view of the catalytic decomposition of H2O2 in waste acid,a small-scale test was designed.The energy-saving optimization potential of the device was studied through process simulation,and a pilot test device was built to verify the catalytic decomposition effect of H2O2.The experimental results show that under the conditions of a reaction temperature of 90℃,reaction time of 60 min,stirring speed of 75 r/min,and dosage of catalyst D of 10 mg/kg,the decomposition rate of H2O2 in the small-scale and pilot test devices can reach more than 99.9%.The first derivative of redox potential can intuitively reflect the reaction progress and be used to determine the endpoint of the H2O2 decomposition reaction.The pilot test device has an obvious energy-saving effect,and the consumption of steam and circulating water can be reduced by 65.55%and 46.18%,respectively.关键词
H2O2分解/氧化还原电位/节能优化Key words
H2O2 decomposition/redox potential/energy-saving optimization分类
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沈伟,李虎,刘利娟,张铁峰..废酸中H2O2催化分解工艺研究[J].化工环保,2025,45(2):302-307,6.