燃料化学学报（中英文）2025，Vol.53Issue(4)：419-433,15.DOI:10.1016/S1872-5813(24)60498-6
基于化学链甲烷重整制氢的钙钛矿载氧体研究综述
A review of research on perovskite oxygen carrier for chemical looping reforming of methane
摘要
Abstract
The chemical looping reforming of methane can simultaneously produce synthesis gas and high-purity hydrogen,and efficiently capture CO2 during the hydrogen production process,which is of great significance for achieving the"dual carbon"goal.The selection of high-performance and low-cost oxygen carriers is crucial for the chemical looping reforming of methane.Due to its abundant oxygen vacancies and good thermal stability,the perovskite oxygen carriers have become a research hotspot as the oxygen carriers required for the chemical looping reforming of methane.In this review,the chemical looping reforming of methane including chemical looping steam methane reforming,chemical looping dry reforming of methane and chemical looping partial oxidation reforming of methane was first introduced.Then,the latest research progress on the Fe based,Ni based and Mn based perovskite type oxygen carriers as well as the supported perovskite oxygen carriers was summarized.Moreover,the pore structure,surface morphology,redox performance,and reaction mechanism of different metal-based perovskite oxygen carriers were analyzed and compared.Finally,the challenges and development prospects faced by perovskite oxygen carriers were summarized.关键词
化学链/甲烷重整/制氢/载氧体/钙钛矿Key words
chemical looping/methane reforming/hydrogen production/oxygen carrier/perovskite分类
能源与动力引用本文复制引用
任金丽,张根宁,沈秋婉,李新海,杜艳秋,陈彬剑,闫敏..基于化学链甲烷重整制氢的钙钛矿载氧体研究综述[J].燃料化学学报（中英文）,2025,53(4):419-433,15.基金项目
The project was supported by Innovation Ability Improvement Project of Shandong Province(2022TSGC2041,2023TSGC0855),Shandong Natural Science Foundation(ZR2021QE065).山东省创新能力提升项目(2022TSGC2041,2023TSGC0855),山东省自然科学基金(ZR2021QE065)资助 （2022TSGC2041,2023TSGC0855）
