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具有多重氢键结合位点的寡聚芳酰胺类凝胶因子的合成及其性能

裴强 徐果 徐文豪 吴晋晋 丁爱祥

信阳师范大学学报(自然科学版)2025,Vol.38Issue(2):125-130,6.
信阳师范大学学报(自然科学版)2025,Vol.38Issue(2):125-130,6.DOI:10.3969/j.issn.2097-583X.2025.02.001

具有多重氢键结合位点的寡聚芳酰胺类凝胶因子的合成及其性能

Synthesis and properties of gelators with multiple hydrogen bonding sites based on oligomeric aromatic amide

裴强 1徐果 1徐文豪 1吴晋晋 1丁爱祥1

作者信息

  • 1. 信阳师范大学 化学化工学院,河南 信阳 464000
  • 折叠

摘要

Abstract

Three gelators(G1,G2 and G3)with strong hydrophobic groups terminating at the end of oligomeric aromatic amide were designed and synthesized.Their structures were characterized by IR,1H NMR,13C NMR and HRMS.The effects of molecular structure and surface roughness on gel properties and hydrophobicity were studied.The results showed that the gel properties of gelator was stronger when there were more flexible groups,such as long alkane chains or polyether chains.The hydrophobicity of xerogel film formed by gelator was enhanced with the increase of hydrophobic groups or the decrease of hydrophilic groups.

关键词

有机凝胶/寡聚芳酰胺/多重氢键/自组装

Key words

organogelator/oligomeric aromatic amide/multiple hydrogen bonds/self-assembled

分类

化学化工

引用本文复制引用

裴强,徐果,徐文豪,吴晋晋,丁爱祥..具有多重氢键结合位点的寡聚芳酰胺类凝胶因子的合成及其性能[J].信阳师范大学学报(自然科学版),2025,38(2):125-130,6.

基金项目

国家自然科学基金项目(21401159) (21401159)

河南省高等学校重点科学研究资助项目(19A150042) (19A150042)

信阳师范大学博士科研启动基金(18077,18072) (18077,18072)

信阳师范大学"南湖学者奖励计划"青年项目 ()

信阳师范大学学报(自然科学版)

1003-0972

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