电化学（中英文）2025，Vol.31Issue(1)：41-56,16.DOI:10.61558/2993-074X.3509
调控锡氧化物基材料功能特性的新见解
New Insights into Controlling the Functional Properties of Tin Oxide-Based Materials
摘要
Abstract
Development of methodologies for fabrications of nanostructured materials that provide control over their microstructur-al features and compositions represents a fundamental step in the advancement of technologies for productions of materials with well-defined functional properties.Pulse electrolysis,a top-down electrochemical approach,has been demonstrated to be a viable method for producing nanostructured materials with a particular efficacy in the synthesis of tin oxides.This method allows for significant control over the composition and shape of the resulting tin oxides particles by modifying the anionic composition of the aqueous electrolyte,obviating the need for additional capping agents in the synthesis process and eliminating the requirement for high-temperature post-treatments.The composition and microstructural characteristics of these oxides are found to be contingent upon the differing stabilities of tin fluoride and chloride complexes,as well as the distinct mechanisms of interaction between chloride and fluoride anions with an oxidized tin surface,which is influ-enced by the varying kosmotropic/chaotropic nature of these anions.The composition and microstructural characteristics of the obtained dispersed tin oxides would thus determine their potential applications as an anode material for lithium-ion batteries,as a photocatalyst,or as an oxyphilic component of a hybrid support for a platinum-containing electrocatalyst.关键词
锡氧化物/脉冲电解/锂离子电池/光催化/燃料电池Key words
Tin oxide/Pulse electrolysis/Lithium-ion battery/Photocatalysis/Fuel cell引用本文复制引用
Alexandra Kuriganova,Nina Smirnova..调控锡氧化物基材料功能特性的新见解[J].电化学（中英文）,2025,31(1):41-56,16.基金项目
This work was supported by the Ministry of Sci-ence and Higher Education of the Russian Federation under Project FENN-2024-0002. （）
