辽宁石油化工大学学报2025，Vol.45Issue(2)：21-27,7.DOI:10.12422/j.issn.1672-6952.2025.02.003
沸石碱溶解液诱导ZSM-5分子筛水热合成研究
Hydrothermal Synthesis of ZSM-5 Induced by Corresponding Alkaline Hydrolysis Products
摘要
Abstract
ZSM-5 has been widely used in the field of petrochemical industry.The extensive use of organic templates in its conventional synthesis process has caused serious problems on environmental and cost.In this paper,the hydrothermal synthesis of ZSM-5 with tetraethyl orthosilicate,aluminum sulfate octadecahydrate and alkaline hydrolysis product of HZSM-5 as silica source,alumina source and structural directing agent,respectively,has been investigated,which aims at developing of new process for green synthesis of zeolites.The synthesized samples were characterized by a series of techniques,such as XRD,TEM,SEM,N2 physical adsorption and TG analysis.It has been shown that successful synthesis of ZSM-5 can be achieved by induction of alkaline hydrolysis product of HZSM-5 in organic template-free system.The prepared sample possesses a relative low crystallinity and specific surface area than ones from conventional process.The study in this paper has provided the chance for combination of green synthesis of zeolites and post-treatment route for synthesis of hierarchical zeolites.关键词
ZSM-5/绿色合成/碱溶解液/无有机模板剂/多级孔Key words
ZSM-5/Green synthesis/Alkaline hydrolysis product/Organic template-free/Hierarchical分类
化学引用本文复制引用
徐文琦,刘一帆,马加新,王锐,姜恒,金长子..沸石碱溶解液诱导ZSM-5分子筛水热合成研究[J].辽宁石油化工大学学报,2025,45(2):21-27,7.基金项目
辽宁省教育厅科学技术研究项目(LJ212410148035) （LJ212410148035）
辽宁石油化工大学人才引进项目(2020XJJL-016). （2020XJJL-016）
