辐射研究与辐射工艺学报2025，Vol.43Issue(2)：41-49,9.DOI:10.11889/j.1000-3436.2024-0069
聚丙烯酰胺接枝聚合物/黄原胶气溶胶固定剂制备及其对碲气溶胶的捕获固定研究
Preparation of polyacrylamide-grafted polymer/xanthan gum aerosol immobilizers and their immobilization for tellurium aerosol capture studies
蒋丹枫 1宋国华 2李雪菲 1苏兴东 1詹杰 1肖梦情 3李银涛3
作者信息
- 1. 中广核研究院有限公司 深圳 518028
- 2. 中国广核集团有限公司 深圳 518000
- 3. 西南科技大学 环境友好能源国家重点实验室 绵阳 621000
- 折叠
摘要
Abstract
Radioactive aerosols(polonium and polonium compounds)generated during the normal operation of lead-bismuth coolants are extremely toxic and radioactive,thus rendering them detrimental to the operation staff and environment.Thus,radioactive polonium aerosols generated during polonium removal must be captured and immobilized.In this study,an aerosol fixative with desirable wettability and capture fixation properties was prepared using compounding xanthan gum(XG)with a grafted polymer polyacrylamide grafted acrylic acid,2-hydroxyethyl acrylate(PAM-g-PAA/PHEA),and a polyacrylamide-based material was used for the substrate.The structure of the aerosol fixative was analyzed and confirmed via infrared spectroscopy,X-ray diffraction,and scanning electron microscopy.The thermal properties,wettability,as well as capture and fixation effects of tellurium(simulated polonium)aerosols were investigated via thermogravimetric analysis,contact-angle measurements,and fixed-sedimentation experiments.The results showed that PAM-g-PAA/PHEA and XG synergistically formed a dual-network structure through hydrogen bonding and that the thermal,wettability,and immobilization properties of the aerosol fixative improved.The optimal addition amount of XG was determined to be 0.05%based on the results of sedimentation experiments,wettability,and fixation rate.At this optimal amount,the aerosol fixing agent exerts the greatest effect on the hydrogen bond and van der Waals forces of tellurium powder.The lowest contact angle is 38.38°,and the tellurium powder infiltrated completely within 80 s.Based on the mass-concentration change,the sedimentation fixation rate is 99.24%,which indicates that atomization fixation is suitable for capturing and fixing radioactive aerosols.The small droplets atomized by the aerosol fixing agent in this study rapidly deposited aerosols,followed by continuous capture and fixation.The results of batch fixed sedimentation verify that this type of aerosol fixing agent is suitable for the capture and fixation of tellurium aerosols,thus providing technical support for the capture and fixation of radioactive polonium aerosols.关键词
黄原胶/双网络/捕获固定/润湿性/固定率Key words
Xanthan gum/Dual network/Capture fixed/Wettability/Fixed rate分类
能源科技引用本文复制引用
蒋丹枫,宋国华,李雪菲,苏兴东,詹杰,肖梦情,李银涛..聚丙烯酰胺接枝聚合物/黄原胶气溶胶固定剂制备及其对碲气溶胶的捕获固定研究[J].辐射研究与辐射工艺学报,2025,43(2):41-49,9.
