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硫酸盐绿锈去除难降解有机物的关键因子研究

王昕 卿三成 薛广海 吴萌 潘社卫

有色金属科学与工程2025,Vol.16Issue(2):223-229,7.
有色金属科学与工程2025,Vol.16Issue(2):223-229,7.DOI:10.13264/j.cnki.ysjskx.2025.02.007

硫酸盐绿锈去除难降解有机物的关键因子研究

Study on the key factors controlling the process in which sulfate green rusts remove bio-refractory organic pollutants

王昕 1卿三成 1薛广海 1吴萌 1潘社卫1

作者信息

  • 1. 矿冶科技集团有限公司,北京 100160
  • 折叠

摘要

Abstract

The removal of refractory and highly toxic organic pollutants in wastewater has become an important issue in the field of environmental governance.The mechanism and influencing factors of the process in which methyl orange and nitrobenzene were removed by sulfate green rust(GR-B)prepared by a semi-intermittent drip-adding method were investigated.The results showed that GR-B had an obvious removal effect on the two water-soluble organic pollutants that were arduous to degrade in nature.After 3 hours,around 89.6%of methyl orange and 96%of nitrobenzene were removed in the reduced system.The optimal reaction conditions were as follows:at 25℃and pH 11,the optimal dosage was 33.6 g/L GR-B and 30 mg/L methyl orange or 100 mg/L nitrobenzene,respectively.By comparing and analyzing COD changes during the removal of methyl orange and nitrobenzene,it was preliminarily concluded that the reaction mechanism of the process in which GR-B was utilized to remove the two organic pollutants was adsorption and chemical reaction,respectively.

关键词

硫酸盐绿锈/甲基橙/硝基苯/半间歇式滴加方法

Key words

sulfate green rust/methyl orange/nitrobenzene/semi-intermittent drip-adding method

分类

冶金工业

引用本文复制引用

王昕,卿三成,薛广海,吴萌,潘社卫..硫酸盐绿锈去除难降解有机物的关键因子研究[J].有色金属科学与工程,2025,16(2):223-229,7.

基金项目

矿冶科技集团有限公司青年科技创新基金资助项目(04-2359) (04-2359)

有色金属科学与工程

OA北大核心

1674-9669

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