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磷石膏主要化学成分及重金属元素分析

王先桥 龚浩擂 龚姝 黄华 王露 范开静

云南化工2025,Vol.52Issue(4):51-54,4.
云南化工2025,Vol.52Issue(4):51-54,4.DOI:10.3969/j.issn.1004-275X.2025.04.12

磷石膏主要化学成分及重金属元素分析

Analysis of theMain Chemical Components and HeavyMetal Elements of Phosphogypsum

王先桥 1龚浩擂 1龚姝 1黄华 1王露 1范开静1

作者信息

  • 1. 国家磷产品质量监督检验中心(湖北),湖北 宜昌 443000
  • 折叠

摘要

Abstract

The chemical composition of phosphogypsum,including the content of major compounds and impurity elements is analyzed,to provide theoretical guidance for the comprehensive utilization risk assessment of phosphogypsum.Taking phosphogypsum and modified phosphogypsum as the research object,the chemical composition and content were determined by X-ray powder diff(XRD),X-ray fluorescence spectrometry(XRF),and inductively coupled plasma emission spectrometry(ICP-OES).The results show the main minerals of phosphogypsum are composed of a mixed phase of dihydrate calcium sulfate,hemihydrate,and anhydrous calcium sulfate,the main impurities are calcium silicate and mixed salts of silicon,aluminum,phosphorus,and fluorine;the main oxides in phosphogypsum include CaO,SO3,SiO2,Fe2 O3,K2 O,Na2 O,Al2 O3,SrO,BaO,P2 O5,TiO2,MgO,CuO,NiO,and the trace elements include Pb,Cd,Cr,Hg,As,Zn Sb,Mn,Mo,V,and the trace elements include Be,Se,Pt,Au,W,Pd,Sn.

关键词

磷石膏/化学成分/重金属/二水硫酸钙/工业固体废物/综合利用

Key words

Phosphogypsum/Chemical Composition/Heavy Metal/Dihydrate Calcium Sulfate/Industrial Solid Waste/Comprehensive Utilization

分类

矿业与冶金

引用本文复制引用

王先桥,龚浩擂,龚姝,黄华,王露,范开静..磷石膏主要化学成分及重金属元素分析[J].云南化工,2025,52(4):51-54,4.

云南化工

1004-275X

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