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β-苯乙醇在烟草秸秆活性炭上的吸附及缓释性能

许克静 张峻松 刘向真 刘语煊 马一琼 郝辉 张智轩 方志辉 梁淼 陈小龙

湖南农业大学学报(自然科学版)2025,Vol.51Issue(2):122-128,7.
湖南农业大学学报(自然科学版)2025,Vol.51Issue(2):122-128,7.

β-苯乙醇在烟草秸秆活性炭上的吸附及缓释性能

Adsorption and sustained release properties of β-phenylethanol using tobacco straw activated carbon

许克静 1张峻松 2刘向真 1刘语煊 2马一琼 1郝辉 1张智轩 1方志辉 2梁淼 2陈小龙1

作者信息

  • 1. 河南中烟工业有限责任公司,河南 郑州 450003
  • 2. 郑州轻工业大学烟草科学与工程学院,河南 郑州 450002
  • 折叠

摘要

Abstract

Tobacco straw activated carbons(TSAC60,TSAC75,TSAC90)were prepared at three activation times(60,75,90 min)by pyrolysis activation method.The adsorption and release behaviors of β-phenylethanol on the three prepared activated carbons(TSAC)were studied,and the influence of pore structure on the adsorption and release behavior of β-phenylethanol was analyzed using a kinetic model.The results showed that the pore structure varied with activation time:microporosity decreased from 66.39%(TSAC60)to 24.81%(TSAC90).Adsorption of β-phenylethanol on TSAC was primarily physical,best fitted by the pseudo-first-order kinetic model,with TSAC60 showing the highest equilibrium adsorption(101.49%)but the lowest rate constant.Non-isothermal heat release analysis indicated enhanced thermal stability,with TSAC60 exhibiting the strongest sustained release,well-described by the Page model.Isothermal release followed the Korsmeyer-Peppas model,dominated by Fickian diffusion;TSAC60 released 27.34%of β-phenylethanol after 35 days.The microporosity of TSAC was the key factor governing adsorption and sustained release performance.

关键词

烟草秸秆/活性炭/β-苯乙醇/吸附/缓释/热稳定性/动力学

Key words

tobacco straw/activated carbon/β-phenylethanol/adsorption/sustained release/thermal stability/dynamics

分类

化学化工

引用本文复制引用

许克静,张峻松,刘向真,刘语煊,马一琼,郝辉,张智轩,方志辉,梁淼,陈小龙..β-苯乙醇在烟草秸秆活性炭上的吸附及缓释性能[J].湖南农业大学学报(自然科学版),2025,51(2):122-128,7.

基金项目

河南中烟工业有限责任公司科研项目(AW2022024) (AW2022024)

湖南农业大学学报(自然科学版)

OA北大核心

1007-1032

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