四川师范大学学报（自然科学版）2025，Vol.48Issue(4)：427-439,13.DOI:10.3969/j.issn.1001-8395.2025.04.001
过渡金属基电极电催化氧化5-羟甲基糠醛为2,5-呋喃二甲酸研究进展
Transition Metal-based Electrodes for Electrocatalytic Oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic Acid
摘要
Abstract
The preparation of value-added chemicals from sustainable biomass resources is of great significance for mitigating fossil fuel depletion.As one of the important bio-based platform molecules from 5-hydroxymethylfurfural(HMF)oxidation,2,5-furandicar-boxylic acid(FDCA)has received widespread attention as a sustainable alternative to petroleum-derived terephthalic acid(TPA).Compared with the traditional thermocatalytic conversion,electrochemical catalysis has the advantages of environmental friendliness,mild reaction conditions and strong controllability of the reaction system,where use in efficient catalysis of HMF to synthesize FDCA can minimize the energy cost and environmental impact to a large extent.Here,we discuss the electrochemical oxidation of HMF,de-scribe the effect of pH on the HMF electrooxidation,and systematically summarize the reaction mechanism(direct and indirect oxida-tion).Then,the research progress as well as advantages and disadvantages of transition metal-based electrodes in HMF electrooxida-tion in the past five years are summarized.In addition,coupled systems that combine HMF electrooxidation with different types of ca-thodic reduction for higher energy utilization are discussed.The purpose of this review is to provide guidance for the utilization of re-newable resources and the production of advanced catalytic electrodes.关键词
5-羟甲基糠醛/2,5-呋喃二甲酸/电化学氧化/过渡金属基催化剂Key words
5-hydroxymethylfurfural/2,5-furandicarboxylic acid(FDCA)/electrochemical oxidation/transition metal-based elec-trodes分类
化学工程引用本文复制引用
漆新华,王浩业,冯艺璇..过渡金属基电极电催化氧化5-羟甲基糠醛为2,5-呋喃二甲酸研究进展[J].四川师范大学学报（自然科学版）,2025,48(4):427-439,13.基金项目
国家自然科学基金(22178181)、天津市自然科学基金(21JCZDJC00180)和中央高校基本科研业务费(南开大学63243129) （22178181）
