物理学报2025，Vol.74Issue(8)：51-68,18.DOI:10.7498/aps.74.20241728
B-样条基组方法在少电子原子结构精密计算中的应用
Applications of B-spline method in precise calculation of structure of few-electron atoms
摘要
Abstract
The precise spectra of few-electron atoms plays a pivotal role in advancing fundamental physics,including the verification of quantum electrodynamics(QED)theory,the determination of the fine-structure constants,and the exploration of nuclear properties.With the rapid development of precision measurement techniques,the demand for atomic structure data has evolved from simply confirming existence to pursuing unprecedented accuracy.To meet the growing needs for precision spectroscopy experiments,we develop a series of high-precision theoretical methods based on B-spline basis sets,such as the non-relativistic configuration interaction(B-NRCI)method,the correlated B-spline basis functions(C-BSBFs)method,and the relativistic configuration interaction(B-RCI)method.These methods use the unique properties of B-spline functions,such as locality,completeness,and numerical stability,to accurately solve the Schrödinger and Dirac equations for few-electron atoms. Our methods yield significant results,particularly for helium and helium-like ions.Using these methods,we obtain accurate energies,polarizabilities,tune-out wavelengths,and magic wavelengths.Specifically,we achieve high-precision measurements of the energy spectra of helium,providing vital theoretical support for conducting related experimental researches.Additionally,we make high-precision theoretical predictions of tune-out wavelengths,paving the way for new tests of QED theory.Furthermore,we propose effective theoretical schemes to suppress Stark shifts,thereby facilitating high-precision spectroscopy experiments of helium The B-spline-basis methods reviewed in this paper prove exceptionally effective in high-precision calculations for few-electron atoms.These methods not only provide crucial theoretical support for precision spectroscopy experiments but also pave the new way for testing QED.Their ability to handle large-scale configuration interactions and incorporate relativistic and QED corrections makes them versatile tools for advancing atomic physics research.In the future,the high-precision theoretical methods based on B-spline basis sets are expected to be extended to cutting-edge fields,such as quantum state manipulation,determination of nuclear structure properties,formation of ultracold molecules,and exploration of new physics,thus continuously promoting the progress of precision measurement physics.关键词
B-样条基组方法/少电子原子/极化率/贝特对数项Key words
B-spline basis sets/few-electron atoms/polarizabilities/Bethe-logarithm引用本文复制引用
张永慧,史庭云,唐丽艳..B-样条基组方法在少电子原子结构精密计算中的应用[J].物理学报,2025,74(8):51-68,18.基金项目
国家自然科学基金(批准号:12174402,12393821,12274423,12274417)、中国科学院先导B项目(批准号:XDB0920100,XDB0920101)和中国科学院稳定支持基础研究领域青年团队计划(批准号:YSBR-055)资助的课题. Project supported by the National Natural Science Foundation of China(Grant Nos.12174402,12393821,12274423,12274417),the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDB0920100,XDB0920101),and the Project for Young Scientists in Basic Research of Chinese Academy of Sciences(Grant No.YSBR-055). （批准号:12174402,12393821,12274423,12274417）
